ChemInform Abstract: STUDIES IN FLUORINATED β-DIKETONES AND RELATED COMPOUNDS. PART VIII. PREPARATION OF SOME NEW PIPERIDINIUM TETRAKIS RARE EARTH 1,3-DIKETONATES AND THEIR FLUORESCENCE AND INFRARED SPECTRAL STUDIES

1977 ◽  
Vol 8 (36) ◽  
pp. no-no
Author(s):  
K. C. JOSHI ◽  
V. N. PATHAK ◽  
S. BHARGAVA ◽  
P. G. SEYBOLD
Keyword(s):  
Rare Earth ◽  
Spectral Studies ◽  
Infrared Spectral ◽  
Related Compounds

Infrared spectral studies of phosphiran and some related compounds

1970 ◽  
Vol 26 (1) ◽  
pp. 249-255 ◽  
Author(s):  
S. Chan ◽  
H. Goldwhite ◽  
H. Keyzer ◽  
R. Tang
Keyword(s):  
Spectral Studies ◽  
Infrared Spectral ◽  
Related Compounds

scholarly journals Collective Optical, FTIR, and Photoluminescence Spectra of CeO2 and/or Sm2O3-Doped Na2O–ZnO–P2O5 Glasses

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
M. A. Marzouk ◽  
H. A. ElBatal ◽  
Y. M. Hamdy ◽  
F. M. Ezz-Eldin
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Spectral Studies ◽  
Luminescence Spectra ◽  
Ir Absorption ◽  
Photoluminescence Spectra ◽  
Absorption Bands ◽  
Infrared Spectral ◽  
Doped Glasses ◽  
The Rare Earth

Glasses with the Na2O–ZnO–P2O5 composition and doped with single CeO2, Sm2O3, or mixed dopants were melted and studied. Collective optical, photoluminescence, and FT-infrared spectral studies were carried out. CeO2-doped glasses show two extra UV absorption bands due to Ce4+ and Ce3+ ions while Sm2O3-doped samples reveal pronounced peaks collected into two segments from 367 to 472 nm and from 950 to 1623 nm which are characteristic of absorption from Sm3+ ions. The mixed dopants glasses show combined UV-visible–near-IR absorption peaks due to cerium (Ce4+, Ce3+) ions and samarium (Sm3+) ions. The photoluminescence spectra (PL) of the single CeO2-doped and Sm2O3-doped glasses and even the mixed dopant sample reveal luminescence spectra after excitation which are characteristic of the rare-earth ions. The intensities for both excited or emitted peaks are found to increase with the increase of the rare-earth percent. FTIR spectra of the glasses show pronounced vibrational peaks related to phosphate groups (Q2 and Q3 units) in accordance with the P2O5 percent (70 mol %).

scholarly journals Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds

2012 ◽  
Vol 9 (1) ◽  
pp. 381-388 ◽  
Author(s):  
Harpreet Kaur ◽  
Baljit Singh
Keyword(s):  
Elemental Analysis ◽  
Electrochemical Synthesis ◽  
Coordination Compounds ◽  
Supporting Electrolyte ◽  
Spectral Studies ◽  
Electrochemical Reactions ◽  
Hydroxybenzoic Acid ◽  
Platinum Cathode ◽  
Infrared Spectral ◽  
Tetrabutylammonium Chloride

Bismuth(III) phenoxides have been synthesized by electrochemical reactions of 1-naphthol, 2-naphthol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2-hydroxybenzoic acid,p-cresol, phenol, resorcinol, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol at sacrificial bismuth anode and inert platinum cathode using tetrabutylammonium chloride as supporting electrolyte. The coordination compounds of these phenols with 1, 10-phenanthroline and 2, 2ʼ-bipyridyl have also been synthesized electrochemically. The solid products separated in the anode compartment have been isolated and characterized by elemental analysis and infrared spectral studies. Current efficiencies of these reactions are quite high.

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