ChemInform Abstract: METAL CATALYSIS IN ORGANIC REACTIONS. PART 13. THE REACTION OF 3-EN-1-YNES WITH TRIALKYLALANES: INFLUENCE OF TRANSITION METAL COMPLEXES

1981 ◽  
Vol 12 (42) ◽  
Author(s):  
A. M. CAPORUSSO ◽  
G. GIACOMELLI ◽  
L. LARDICCI
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Organic Reactions ◽  
Metal Catalysis

scholarly journals Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes

2017 ◽  
Vol 375 (2101) ◽  
pp. 20170002 ◽  
Author(s):  
R. Morris Bullock ◽  
Geoffrey M. Chambers
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Complexes ◽  
Main Group ◽  
Lewis Base ◽  
Metal Compounds ◽  
Metal Catalysis ◽  
Heterolytic Cleavage ◽  
Lewis Pairs

This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

scholarly journals Programming cascade reactions interfacing biocatalysis with transition-metal catalysis in Deep Eutectic Solvents as biorenewable reaction media

2018 ◽  
Vol 20 (15) ◽  
pp. 3468-3475 ◽  
Author(s):  
Luciana Cicco ◽  
Nicolás Ríos-Lombardía ◽  
María J. Rodríguez-Álvarez ◽  
Francisco Morís ◽  
Filippo M. Perna ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Deep Eutectic Solvents ◽  
Cascade Reactions ◽  
Transition Metal Catalysis ◽  
Secondary Alcohols ◽  
Metal Catalysis ◽  
Eutectic Mixtures ◽  
Reaction Media

Transition-metal complexes and purified ketoreductases work together in eutectic mixtures for the synthesis of enantiopure secondary alcohols.

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