ChemInform Abstract: A Kinetic Study of the Lewis Base Promoted Migratory Insertion Reaction of fac-[(diars)Fe(CO)3CH3]+. Direct Observation of a Solvent Coordinated Intermediate.

Chemischer Informationsdienst ◽

10.1002/chin.198322297 ◽

1983 ◽

Vol 14 (22) ◽

Author(s):

C. R. JABLONSKI ◽

Y. P. WANG

Keyword(s):

Kinetic Study ◽

Direct Observation ◽

Insertion Reaction ◽

Migratory Insertion

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A kinetic study of the lewis base promoted migratory insertion reaction of fac-[(diars)Fe(CO)3CH3]+. Direct observation of a solvent coordinated intermediate

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)83565-3 ◽

1983 ◽

Vol 69 ◽

pp. 147-153 ◽

Author(s):

C.R. Jablonski ◽

Yu Pin Wang

Keyword(s):

Kinetic Study ◽

Direct Observation ◽

Insertion Reaction ◽

Migratory Insertion

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A Mechanistic Study of the Migratory Insertion Reaction: A Computational Chemistry Exercise

Journal of Chemical Education ◽

10.1021/ed300526k ◽

2013 ◽

Vol 90 (10) ◽

pp. 1396-1400 ◽

Author(s):

Craig D. Montgomery

Keyword(s):

Computational Chemistry ◽

Insertion Reaction ◽

Mechanistic Study ◽

Migratory Insertion

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Highly Chemo-, Regio-, and Stereoselective Carbon−Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5-Dienes and 1,5-Enynes

Journal of the American Chemical Society ◽

10.1021/ja990266+ ◽

1999 ◽

Vol 121 (48) ◽

pp. 11223-11224 ◽

Author(s):

Yves Dumond ◽

Ei-ichi Negishi

Keyword(s):

Bond Formation ◽

Insertion Reaction ◽

Carbon Bond ◽

Novel Synthesis ◽

Carbon Carbon Bond ◽

Migratory Insertion

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Electronic Effects on the β-Alkyl Migratory Insertion Reaction ofpara-Substituted Styrene Methyl Palladium Complexes

Journal of the American Chemical Society ◽

10.1021/ja9527434 ◽

1996 ◽

Vol 118 (10) ◽

pp. 2436-2448 ◽

Author(s):

Francis C. Rix ◽

Maurice Brookhart ◽

Peter S. White

Keyword(s):

Palladium Complexes ◽

Insertion Reaction ◽

Electronic Effects ◽

Migratory Insertion

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Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex

Journal of the American Chemical Society ◽

10.1021/ja00402a079 ◽

1981 ◽

Vol 103 (12) ◽

pp. 3612-3614 ◽

Author(s):

Wayne P. Weiner ◽

Mary Ann White ◽

Robert G. Bergman

Keyword(s):

Metal Complex ◽

Direct Observation ◽

Migratory Insertion

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Direct observation of an isopolyhalomethane O–H insertion reaction with water: Picosecond time-resolved resonance Raman (ps-TR3) study of the isobromoform reaction with water to produce a CHBr2OH product

The Journal of Chemical Physics ◽

10.1063/1.1640997 ◽

2004 ◽

Vol 120 (7) ◽

pp. 3323-3332 ◽

Author(s):

Wai Ming Kwok ◽

Cunyuan Zhao ◽

Yun-Liang Li ◽

Xiangguo Guan ◽

David Lee Phillips

Keyword(s):

Direct Observation ◽

Resonance Raman ◽

Insertion Reaction ◽

Time Resolved ◽

Reaction With Water

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ChemInform Abstract: REACTION OF TRANS-DIHYDRIDO-BIS(TRICYCLOHEXYLPHOSPHINE)PLATINUM WITH CARBON DISULFIDE. KINETIC STUDY OF THE INSERTION REACTION AND X-RAY STRUCTURE OF TRANS-HYDRIDODITHIOFORMATO-BIS(TRICYCLOHEXYLPHOSPHINE)PLATINUM

Chemischer Informationsdienst ◽

10.1002/chin.197632058 ◽

1976 ◽

Vol 7 (32) ◽

pp. no-no

Author(s):

A. ALBINATI ◽

A. MUSCO ◽

G. CARTURAN ◽

G. STRUKUL

Keyword(s):

Kinetic Study ◽

Carbon Disulfide ◽

Insertion Reaction ◽

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Migratory insertion reaction in alkenyl ruthenium(II) complexes containing a trifluoroacetate ligand. X-ray structure of the Ru(η2- O2CCF3)(η1-OCCHCHtBu)(CO)(PPh3)2 complex

Inorganic Chemistry Communications ◽

10.1016/s1387-7003(99)00095-7 ◽

1999 ◽

Vol 2 (8) ◽

pp. 364-367 ◽

Author(s):

Lluı̈sa Matas ◽

Josep Muniente ◽

Josep Ros ◽

Ángel Alvarez-Larena ◽

Joan F. Piniella

Keyword(s):

Insertion Reaction ◽

X Ray ◽

Migratory Insertion

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A Kinetic Study of Ethylene and 1-Hexene Homo- and Copolymerization Catalyzed by a Silica-Supported Cr(IV) Complex: Evidence for Propagation by a Migratory Insertion Mechanism

Journal of the American Chemical Society ◽

10.1021/ja001693m ◽

2000 ◽

Vol 122 (37) ◽

pp. 8968-8976 ◽

Author(s):

Jamila Amor Nait Ajjou ◽

Susannah L. Scott

Keyword(s):

Kinetic Study ◽

Migratory Insertion ◽

Insertion Mechanism

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Syntheses and reactivity of square-planar Rh(I) complexes, LRh(CO) (L = unsymmetric tridentate chelating pyrazolylgallate ligand). X-ray crystal structures of [Me2Gapz(OCH2CH2NH2)]Rh(CO) and [Me2Gapz(OCH2CH2NMe2)]Rh(COMe)I (pz = pyrazolyl, N2C3H3)

Canadian Journal of Chemistry ◽

10.1139/v85-501 ◽

1985 ◽

Vol 63 (11) ◽

pp. 3019-3026 ◽

Author(s):

Brenda M. Louie ◽

Steven J. Rettig ◽

Alan Storr ◽

James Trotter

Keyword(s):

Crystal Structures ◽

Least Square ◽

Insertion Reaction ◽

Space Group ◽

Physical Measurements ◽

Square Planar ◽

Migratory Insertion ◽

Complex Crystal

The syntheses and characterization of a number of square-planar Rh(I) monocarbonyl complexes incorporating un-symmetrical, tridentate, pyrazolylgallate ligands in a meridional coordination mode are described. Oxidative addition reactions of these complexes are detailed and a facile migratory insertion reaction, following the addition of methyl iodide, has resulted in a five-coordinate square-pyramidal Rh(III) acetyl complex. Crystal structures of two compounds are presented, [Me2Gapz(OCH2CH2NH2)]Rh(CO) and [Me2Gapz(OCH2CH2NMe2)]Rh(COMe)I, and confirm the molecular arrangements predicted on the basis of other physical measurements. Crystals of the former are monoclinic, a = 10.212(2), b = 7.8484(5), c = 16.733(2) Å, β = 105.133(6)°, z = 4, space group P21/c; and those of the latter are monoclinic, a = 10.0960(11), b = 11.5352(8), c = 15.871(2) Å, β = 105.764(6)°, z = 4, space group P21/n. Both structures were solved by conventional heavy atom methods and were refined by full-matrix least-square procedures to R = 0.026 and 0.036, respectively, for 2142 and 2941 reflections with I ≥ 3σ(I).

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