ChemInform Abstract: SYNTHESIS AND X-RAY STRUCTURAL STUDIES ON THE RHODIUM-RUTHENIUM CLUSTER COMPOUNDS (RURH3(μ3-CO)2(CO)3(η-C5ME5)3) AND (RURH2(μ-CO)(μ3-CO)(CO)2(η4-C8H10)(η-C5ME5)2)

1985 ◽  
Vol 16 (32) ◽  
Author(s):  
L. J. FARRUGIA ◽  
J. C. JEFFERY ◽  
C. MARSDEN ◽  
F. G. A. STONE
Author(s):  
James A. Lake

The understanding of ribosome structure has advanced considerably in the last several years. Biochemists have characterized the constituent proteins and rRNA's of ribosomes. Complete sequences have been determined for some ribosomal proteins and specific antibodies have been prepared against all E. coli small subunit proteins. In addition, a number of naturally occuring systems of three dimensional ribosome crystals which are suitable for structural studies have been observed in eukaryotes. Although the crystals are, in general, too small for X-ray diffraction, their size is ideal for electron microscopy.


2003 ◽  
Vol 58 (9) ◽  
pp. 916-921 ◽  
Author(s):  
Amitabha Datta ◽  
Samiran Mitra ◽  
Georgina Rosair

Two new bimetallic complexes [Zn(phen)3][Fe(CN)5(NO)] · 2 H2O · 0.25 MeOH, (1) and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)] · 0.5 H2O, (2), have been isolated (where phen = 1,10-phenanthroline and bipy = bipyridyl) and characterised by X-ray crystallography [as the 2 H2O · 0.25 CH3OH solvate for (1) and hemihydrate for (2)] infrared spectroscopy and thermogravimetric analysis. Substitution of phenanthroline for bipyridyl resulted in a cyano-bridged bimetallic species rather than two discrete mononuclear metal complexes. The bond angles of Fe-N-O were shown to be practically linear for both 1 [179.2(7)°] and 2 [178.3(3)°], and the Zn atoms have distorted octahedral geometry. The solvent molecules in both crystal lattices take part in forming hydrogen-bonded networks.


1980 ◽  
Vol 63 (7) ◽  
pp. 2071-2086 ◽  
Author(s):  
Herbert Motschi ◽  
Cornelius Nussbaumer ◽  
Paul S. Pregosin ◽  
Fiorella Bachechi ◽  
Pasquale Mura ◽  
...  

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