ChemInform Abstract: Gas-Phase Studies of Alkane Oxidation by Transition-Metal Oxides. Selective Oxidation by CrO+.

ChemInform ◽  
1987 ◽  
Vol 18 (15) ◽  
Author(s):  
H. KANG ◽  
J. L. BEAUCHAMP
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Gas Phase ◽  
Selective Oxidation ◽  
Transition Metal Oxides ◽  
Alkane Oxidation

scholarly journals Selective Oxidation of Glycerol Using 3% H2O2 Catalyzed by Supported Nano-Au Catalysts

Catalysts ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 505 ◽  
Author(s):  
Xiaoli Wang ◽  
Gongde Wu ◽  
Tongfa Jin ◽  
Jie Xu ◽  
Shihao Song
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Selective Oxidation ◽  
Mixed Oxide ◽  
Transition Metal Oxides ◽  
Mixed Oxides ◽  
Catalytic Performance ◽  
Glyceric Acid ◽  
Glycerol Conversion ◽  
Composition And Structure

A series of transition metal oxides or mixed oxides supported nano-Au catalysts were prepared for the selective oxidation of glycerol to glyceric acid using 3% H2O2. It was found that the composition and structure of supports significantly influenced the catalytic performance of catalysts. The mesoporous trimetal mixed oxide (CuNiAlO) supported nano-Au catalysts were more active in comparison with the others. In the present catalytic system, the highest glycerol conversion was 90.5%, while the selectivity of glyceric acid could reach 72%. Moreover, the catalytic performance remained after 11 times of reaction.

Onset Conditions for Gas Phase Reaction and Nucleation in the CVD of Transition Metal Oxides

1991 ◽  
Vol 250 ◽  
Author(s):  
J. Collins ◽  
D. E. Rosner ◽  
J. Castillo
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Gas Phase ◽  
Transition Metal Oxides ◽  
Film Theory ◽  
Operating Conditions ◽  
Particle Nucleation ◽  
Phase Reaction ◽  
Homogeneous Reaction ◽  
Gas Phase Reaction

AbstractA combined experimental/theoretical study is presented of the onset conditions for gas phase reaction and particle nucleation in hot substrate/cold gas CVD of transition metal oxides. Homogeneous reaction onset conditions are predicted using a simple high activation energy reacting gas film theory. Experimental tests of the basic theory are underway using an axisymmetric impinging jet CVD reactor. No “vapor phase ignition” has yet been observed in the TiCl4/O2 system under accessible operating conditions (below substrate temperature Tw=1700 K) and further experiments are planned using more reactive feed materials. The goal of this research is to provide CVD reactor design and operation guidelines for achieving acceptable deposit microstructures at the maximum deposition rate while simultaneously avoiding homogeneous reaction/nucleation and diffusional limitations.

Interaction of perovskite-like compounds based on transition-metal oxides with gas phase at T = 200–400°C

2014 ◽  
Vol 115 (6) ◽  
pp. 547-556 ◽  
Author(s):  
N. A. Zyuzeva ◽  
I. B. Bobylev ◽  
S. V. Naumov ◽  
E. P. Romanov
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Gas Phase ◽  
Transition Metal Oxides

Redox-Active Zeolitic Transition Metal Oxides Based on ε-Keggin Units for Selective Oxidation

2019 ◽  
Vol 58 (9) ◽  
pp. 6283-6293 ◽  
Author(s):  
Zhenxin Zhang ◽  
Satoshi Ishikawa ◽  
Qianqian Zhu ◽  
Toru Murayama ◽  
Masahiro Sadakane ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Selective Oxidation ◽  
Transition Metal Oxides ◽  
Redox Active
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