ChemInform Abstract: Synthesis, Characterization, and Oxygen Atom Transfer Reactions of (HB(Me2C3N2H)3)MoO(S2P(OR)2) and (HB(Me2C3N2H)3)MoO2(η1-S2P(OEt)2).

ChemInform ◽  
1988 ◽  
Vol 19 (51) ◽  
Author(s):  
S. A. ROBERTS ◽  
C. G. YOUNG ◽  
W. E. JUN. CLELAND ◽  
R. B. ORTEGA ◽  
J. H. ENEMARK
Keyword(s):  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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