ChemInform Abstract: New Synthetic Transformations via Organoboron Compounds

: Iodine(III)-based reagents has been broadly used in oxidative reactions for the structural functionalization with several functional groups. Among the more relevant and useful synthetic transformations using these hypervalent γ 3 -reagents, it can be found the fluorination, chlorination, bromination as well as the iodination protocols. Herein, we present some of the most representatives oxidative halogenation procedures of arenes, olefins and alkynes dating from the oldest to the more recent advances in the area, highlighting the discovery and application of new iodine(III)-based halogenating species.

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Organoboron Compounds Towards Asymmetric Pericyclic Reaction; Exploitation to Bioactive Molecule Synthesis

Asian Journal of Organic Chemistry ◽

10.1002/ajoc.202100092 ◽

2021 ◽

Author(s):

Santanu Panda ◽

Kanak Kanti Das ◽

Parveen Kumar ◽

Debraj Ghorai ◽

Buddhadeb Mondal

Keyword(s):

Organoboron Compounds ◽

Bioactive Molecule ◽

Pericyclic Reaction

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Chan–Lam-Type C–S Coupling Reaction by Sodium Aryl Sulfinates and Organoboron Compounds

Organic Letters ◽

10.1021/acs.orglett.1c02299 ◽

2021 ◽

Author(s):

Long Yin Lam ◽

Cong Ma

Keyword(s):

Coupling Reaction ◽

Organoboron Compounds ◽

Type C

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Incorporation of the pentafluorosulfanyl group through common synthetic transformations

Monatshefte für Chemie - Chemical Monthly ◽

10.1007/s00706-021-02760-4 ◽

2021 ◽

Vol 152 (4) ◽

pp. 449-459

Author(s):

Hugh G. Hiscocks ◽

Dylan Lee Yit ◽

Giancarlo Pascali ◽

Alison T. Ung

Keyword(s):

Synthetic Transformations

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Transition-metal catalyzed carboxylation of organoboron compounds with CO2

Journal of CO2 Utilization ◽

10.1016/j.jcou.2020.101403 ◽

2021 ◽

Vol 45 ◽

pp. 101403

Author(s):

Wei Xu ◽

Danjun Guo ◽

Abdol Ghaffar Ebadi ◽

Mohsen Toughani ◽

Esmail Vessally

Keyword(s):

Transition Metal ◽

Organoboron Compounds ◽

Transition Metal Catalyzed ◽

Metal Catalyzed

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Perspective of Organoboron Chemistry

Synlett ◽

10.1055/a-1405-7012 ◽

2021 ◽

Author(s):

Lingbing Kong ◽

Chunming Cui

Keyword(s):

Recent Progress ◽

Main Group ◽

Future Research ◽

Materials Chemistry ◽

Organoboron Compounds ◽

The Future ◽

Research Hotspots

Organoboron compounds play prominent roles in structural, synthetic and materials chemistry because the boron atoms may feature electrophilic, amphiphilic and nucleophilic characters. This perspective briefly describes the most recent progress in organoboron chemistry by focusing on both new advent boron molecules and their applications, which greatly inspire the interest of main group chemists. Meanwhile, the future research hotspots based on these pioneering results are also discussed.

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