ChemInform Abstract: Novel Chiral Bis-dipolar 6,6′-Disubstituted Binaphthol Derivatives for Second-Order Nonlinear Optics: Synthesis and Linear and Nonlinear Optical Properties.

ChemInform ◽  
2010 ◽  
Vol 27 (45) ◽  
pp. no-no
Author(s):  
H.-J. DEUSSEN ◽  
E. HENDRICKX ◽  
C. BOUTTON ◽  
D. KROG ◽  
K. CLAYS ◽  
...  
2004 ◽  
Vol 13 (03n04) ◽  
pp. 423-426 ◽  
Author(s):  
L. SANGUINET ◽  
S. AHMED ◽  
J. L. POZZO ◽  
V. RODRIGUEZ ◽  
F. ADAMIETZ

New acidochromic and photochromic compounds with nonlinear optical properties have been designed and synthesized. The hyperpolarizabilities of the zwitterionic colored forms have been quantified with polarized hyper-Rayleigh scattering experiments. The static value of oxazolidino-indoline 2 is found to be as high as Disperse Red One. This opens the way to novel multi-addressable NLO-systems.


RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 84643-84656 ◽  
Author(s):  
Sarbjeet Kaur ◽  
Sugandha Dhoun ◽  
Griet Depotter ◽  
Paramjit Kaur ◽  
Koen Clays ◽  
...  

Thermally stable ferrocene-DPP dyads exhibit non-zero dipole moments as well as negative solvatochromism and show structure dependent second-order nonlinear polarizabilities.


2009 ◽  
Vol 48 (14) ◽  
pp. 6534-6547 ◽  
Author(s):  
Gulliver T. Dalton ◽  
Marie P. Cifuentes ◽  
Laurance A. Watson ◽  
Simon Petrie ◽  
Robert Stranger ◽  
...  

Proceedings ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 4 ◽  
Author(s):  
Rosa M. F. Batista ◽  
Susana P. G. Costa ◽  
Michael Belsley ◽  
M. Manuela M. Raposo

New push-pull second harmonic generation (SHG) chromophores 2 were synthesized in order to study their linear and nonlinear optical properties. The donor-acceptor π-conjugated systems 2 were prepared in good to excellent yields by a simple aldol-type condensation of the precursor aldehydes 1 with 6-nitro-2-methyl-1,3-benzothiazole in the presence of NaOH. Hyper-Rayleigh scattering in dioxane solutions was used to evaluate their second-order nonlinear optical properties. The experimental results showed that the optical (linear and nonlinear) properties are influenced by the electron-donor strength of the groups of the π-conjugated bridge. The vinyl-benzothiazole derivative 2b, with methoxyl as the donor group, exhibited the largest first hyperpolarizability β (1660 × 10−30 esu, 40 times greater than the standard reference pNA molecule) and the highest decomposition temperature (Td = 360 °C). The good balance between nonlinearity and thermal stability makes this compound a promising candidate as second harmonic generator (SHG) for nonlinear optics.


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