ChemInform Abstract: Stereo- and Chemoselective Transfer Hydrogenation of Carbonyl Groups with RuCl2(PPh3)3 and BINAP-Ru as Catalysts and Et3NH+H2PO- 2×1, 5 H2O as a Hydrogen Donor.

ChemInform ◽  
2010 ◽  
Vol 27 (52) ◽  
pp. no-no
Author(s):  
B. T. KHAI ◽  
A. ARCELLI
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Carbonyl Groups

Transfer Hydrogenation of Carbonyl Groups, Imines and N ‐Heterocycles Catalyzed by Simple, Bipyridine‐Based Mn I Complexes

ChemCatChem ◽  
2019 ◽  
Vol 11 (16) ◽  
pp. 3844-3852 ◽  
Author(s):  
Abhishek Dubey ◽  
S. M. Wahidur Rahaman ◽  
Robert R. Fayzullin ◽  
Julia R. Khusnutdinova
Keyword(s):  
Transfer Hydrogenation ◽  
Carbonyl Groups

Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation

2015 ◽  
Vol 48 (2) ◽  
pp. 388-398 ◽  
Author(s):  
Chen Zhu ◽  
Kodai Saito ◽  
Masahiro Yamanaka ◽  
Takahiko Akiyama
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation

scholarly journals Manganese Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxamide Ligands

Synlett ◽  
2019 ◽  
Vol 30 (04) ◽  
pp. 503-507 ◽  
Author(s):  
Jacob Schneekönig ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Isopropyl Alcohol ◽  
Ruthenium Catalyst ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Reaction Conditions ◽  
Active Systems ◽  
Manganese Catalysts

The asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated in situ from [MnBr(CO)5] and inexpensive C 2-symmeric bisoxalamide ligands. Under the optimized reaction conditions, the Mn-derived catalyst gave higher enantioselectivity compared with the related ruthenium catalyst.

Magnesium Aluminate Supported Cu Catalyst for Selective Transfer Hydrogenation of Biomass Derived Furfural to Furfuryl Alcohol with Formic Acid as Hydrogen Donor

2019 ◽  
Vol 4 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Peddinti Nagaiah ◽  
Paleti Gidyonu ◽  
Muppala Ashokraju ◽  
Madduluri Venkata Rao ◽  
Prathap Challa ◽  
...  
Keyword(s):  
Formic Acid ◽  
Furfuryl Alcohol ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Magnesium Aluminate ◽  
Selective Transfer ◽  
Cu Catalyst

Alternative Energy Input for Transfer Hydrogenation using Iridium NHC Based Catalysts in Glycerol as Hydrogen Donor and Solvent

2012 ◽  
Vol 31 (10) ◽  
pp. 3911-3919 ◽  
Author(s):  
Arturo Azua ◽  
Jose A. Mata ◽  
Eduardo Peris ◽  
Frederic Lamaty ◽  
Jean Martinez ◽  
...  
Keyword(s):  
Alternative Energy ◽  
Energy Input ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation

Palladium-catalyzed simple and efficient hydrogenative cleavage of azo compounds using recyclable polymer-supported formate

2005 ◽  
Vol 83 (5) ◽  
pp. 517-520 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R Srinivasa ◽  
D Channe Gowda
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Azo Compounds ◽  
Catalytic Transfer Hydrogenation ◽  
Palladium Catalyzed ◽  
Catalytic Transfer ◽  
Polymer Supported

Palladium-catalyzed room temperature transfer hydrogenation of azo compounds using recyclable polymer-supported formate as the hydrogen donor produces corresponding amine(s) in excellent yields (88%–98%). This method was found to be highly facile with selectivity over a number of other functional groups such as halogen, alkene, nitrile, carbonyl, amide, methoxy, and hydroxyl.Key words: azo compounds, catalytic transfer hydrogenation, polymer-supported formate, 10% Pd-C, amines.

Asymmetric transfer hydrogenation of imines in water/methanol co-solvent system and mechanistic investigation by DFT study

RSC Advances ◽  
2014 ◽  
Vol 4 (86) ◽  
pp. 46351-46356 ◽  
Author(s):  
Vaishali S. Shende ◽  
Savita K. Shingote ◽  
Sudhindra H. Deshpande ◽  
Nishamol Kuriakose ◽  
Kumar Vanka ◽  
...  
Keyword(s):  
Solvent System ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Dft Study ◽  
Asymmetric Transfer Hydrogenation ◽  
Mechanistic Investigation

Asymmetric transfer hydrogenation of various cyclic imines proceeded efficiently with H2O/MeOH (1 : 1, v/v) co-solvent media in 20 min with excellent yields and enantioselectivities by using Rh–TsDPEN catalyst and HCOONa as a hydrogen donor.

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