ChemInform Abstract: Titanium-Substituted Zeolite Beta: An Efficient Catalyst in the Oxy-Functionalization of Cyclic Alkenes Using Hydrogen Peroxide in Organic Solvents.

ChemInform ◽  
2010 ◽  
Vol 30 (4) ◽  
pp. no-no
Author(s):  
E. G. DEROUANE ◽  
G. J. HUTCHINGS ◽  
W. F. MBAFOR ◽  
S. M. ROBERTS
1996 ◽  
Vol 61 (12) ◽  
pp. 1798-1804 ◽  
Author(s):  
Albert Demonceau ◽  
François Simal ◽  
Corine A. Lemoine ◽  
Alfred F. Noels ◽  
Igor T. Chizhevsky ◽  
...  

The title compound was found to be an efficient catalyst for the selective cyclopropanation of activated olefins by ethyl diazoacetate. The cyclopropane yields range from moderate to good (75 to 95%) for activated olefins such as styrene and styrene derivatives, but are rather low (20 to 30%) for non-activated olefins such as terminal and cyclic alkenes. In the intermolecular competition, styrene was 45 times more reactive than cyclooctene. In all cases, trans (exo) cyclopropane predominated over the cis (endo) isomer.


2021 ◽  
Author(s):  
Xingyu Yang ◽  
Xu Li ◽  
Jinxiang Dong

A convenient, scalable, benign, and efficient epoxidation method based on farringtonite, without the use of transition metals, was developed for the first time.


2017 ◽  
Vol 7 (23) ◽  
pp. 5733-5740 ◽  
Author(s):  
Yudong Xue ◽  
Weiquan Cai ◽  
Shili Zheng ◽  
Wenyi Yan ◽  
Jiugang Hu ◽  
...  

Novel W-doped MoS2 electrocatalysts have been successfully fabricated through a facile one-pot solvothermal method and employed for the hydrogen peroxide reduction reaction (HPRR) in emerging alkaline H2O2-based fuel cells.


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