A Rapid, Solvent-Free, Ligandless and Mild Method for Preparing Aromatic Ketones from Acyl Chlorides and Arylboronic Acids via a Suzuki—Miyaura Type of Coupling Reaction.

ChemInform ◽  
2006 ◽  
Vol 37 (7) ◽  
Author(s):  
B. P. Bandgar ◽  
A. V. Patil
Keyword(s):  
Coupling Reaction ◽  
Solvent Free ◽  
Aromatic Ketones ◽  
Acyl Chlorides ◽  
Arylboronic Acids

Eco-friendly Suzuki–Miyaura coupling of arylboronic acids to aromatic ketones catalyzed by the oxime-palladacycle in biosolvent 2-MeTHF

2016 ◽  
Vol 40 (4) ◽  
pp. 3119-3123 ◽  
Author(s):  
Manoj Mondal ◽  
Utpal Bora
Keyword(s):  
Green Chemistry ◽  
Sugar Cane ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Aromatic Ketones ◽  
Acyl Chlorides ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction ◽  
Reaction Proceeds ◽  
Aryl Ketones

Oxime-palladacycle catalyzed aerobic cross-coupling reaction of arylboronic acids and acyl chlorides to yield aryl ketones was developed. The reaction proceeds efficiently in 2-MeTHF, which is derived from corncobs, sugar cane, and fulfils the 3rd, 5th and 7th principles of Green Chemistry.

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