Catalytic Oxidation of Alcohols with Polymer-Supported Ruthenium Complex under Mild Conditions.

A novel strategy for catalytic oxidation of a variety of benzylic, allylic, propargylic, and aliphatic alcohols to the corresponding aldehydes or ketones has been successfully developed.

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Catalytic Oxidation of Hydrocarbons with O2 or H2O2 Using a Sterically Hindered Ruthenium Complex

Journal of the American Chemical Society ◽

10.1021/ja00085a023 ◽

1994 ◽

Vol 116 (6) ◽

pp. 2424-2429 ◽

Cited By ~ 151

Author(s):

Alan S. Goldstein ◽

Robert H. Beer ◽

Russell S. Drago

Keyword(s):

Catalytic Oxidation ◽

Ruthenium Complex ◽

Oxidation Of Hydrocarbons ◽

Sterically Hindered

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Oxidation of 2-methylpyrroles with perchlorinated iron(III) metalloporphyrin catalysts: a versatile synthesis of symmetric and asymmetric dipyrromethanes

Canadian Journal of Chemistry ◽

10.1139/v98-190 ◽

1998 ◽

Vol 76 (10) ◽

pp. 1467-1473 ◽

Cited By ~ 2

Author(s):

Veranja Karunaratne ◽

David Dolphin

Keyword(s):

Catalytic Oxidation ◽

Allylic Alcohols ◽

The Novel ◽

Efficient Synthesis ◽

Mild Conditions ◽

Metalloporphyrin Catalysts

A variety of substituted 2-methylpyrroles (3-8) were oxidized using the metalloporphyrin catalysts iron(III) meso-tetra(2,6-dichloro-3-sulphonatophenyl)-β-octachloroporphyrin chloride 1 and iron(III) meso-tetra(2,6-dichlorophenyl)-β-octachloroporphyrin chloride 2 under very mild conditions. Treatment of the resulting allylic alcohols 3a-8a with α-free pyrroles 9 and 10 resulted in a very efficient synthesis of the corresponding dipyrromethanes 3b-8b and 3c-8c. Furthermore, the above allylic alcohols when treated with furfurylamine produced the novel (2-furylmethyl)-2-pyrrolylmethylamines 3d-8d.Key words: catalytic oxidation, metalloporphyrins, pyrroles, dipyrromethanes, polyhalogenated porphyrins.

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4-OH-TEMPO/TCQ/TBN/HCl: A Metal-Free Catalytic System for Aerobic Oxidation of Alcohols under Mild Conditions

Chinese Journal of Chemistry ◽

10.1002/cjoc.201500357 ◽

2015 ◽

Vol 33 (9) ◽

pp. 1019-1023 ◽

Cited By ~ 4

Author(s):

Yanli Dong ◽

Xiaomei Zhao ◽

Renhua Liu

Keyword(s):

Catalytic System ◽

Aerobic Oxidation ◽

Metal Free ◽

Mild Conditions ◽

Oxidation Of Alcohols

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Catalytic Oxidation of Alcohols Using a 2,2,6,6-Tetramethylpiperidine-N -hydroxyammonium Cation

European Journal of Organic Chemistry ◽

10.1002/ejoc.201801718 ◽

2018 ◽

Vol 2019 (6) ◽

pp. 1413-1417 ◽

Cited By ~ 8

Author(s):

Shelli A. Miller ◽

Kathryn A. Bisset ◽

Nicholas E. Leadbeater ◽

Nicholas A. Eddy

Keyword(s):

Catalytic Oxidation ◽

Oxidation Of Alcohols

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Synthesis of a Ruthenium Complex Based on 2,6-Bis[1-(Pyridin-2-yl)-1H-Benzo[d]Imidazol-2-yl]Pyridine and Catalytic Oxidation of (1H-Benzo[d]-Imidazol-2-yl)Methanol to 1H-Benzo[d]Imidazole-2-Carbaldehyde with H2O2

Journal of Chemical Research ◽

10.3184/174751917x14858862342106 ◽

2017 ◽

Vol 41 (2) ◽

pp. 88-92

Author(s):

Shenggui Liu ◽

Rongkai Pan ◽

Wenyi Su ◽

Guobi Li ◽

Chunlin Ni

Keyword(s):

Reaction Time ◽

Catalytic Oxidation ◽

Reaction Temperature ◽

Ruthenium Complex ◽

Reaction Conditions ◽

Molar Ratios ◽

Optimal Reaction

2,6-Bis[1-(pyridin-2-yl)-1H-benzo[d]-imidazol-2-yl]pyridine (bpbp), which has been synthesised by intramolecular thermocyclisation of N2,N6-bis[2-(pyridin-2-ylamino)phenyl]pyridine-2,6-dicarboxamide, reacts with sodium pyridine-2,6-dicarboxylate (pydic) and RuCl3 to give [Ru(bpbp)(pydic)] which can catalyse the oxidation of (1H-benzo[d]imidazol-2-yl)methanol to 1H-benzo[d]imidazole-2-carbaldehyde by H2O2. The optimal reaction conditions were: molar ratios of catalyst to substrate to H2O2 set at 1: 1000: 3000; reaction temperature 50 °C; reaction time 5 h. The yield of (1H-benzo[d]imidazol-2-yl) methanol was 70%.

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Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)

Organometallics ◽

10.1021/om100807b ◽

2010 ◽

Vol 29 (23) ◽

pp. 6433-6442 ◽

Cited By ~ 96

Author(s):

Pradhumn Singh ◽

Ajai K. Singh

Keyword(s):

Catalytic Oxidation ◽

Transfer Hydrogenation ◽

Sandwich Complexes ◽

Oxidation Of Alcohols ◽

Half Sandwich

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The Chemoselective Reduction of Isoxazolineγ-Lactams Through Iminium Aza-Diels-Alder Reactions: A Short-Cut Synthesis of Aminols as Valuable Intermediates towards Nucleoside Derivatives

The Scientific World JOURNAL ◽

10.1100/2012/643647 ◽

2012 ◽

Vol 2012 ◽

pp. 1-10

Author(s):

Misal Giuseppe Memeo ◽

Mariella Mella ◽

Paolo Quadrelli

Keyword(s):

Catalytic Oxidation ◽

Ring Opening ◽

Diels Alder ◽

Mild Conditions ◽

Nucleoside Synthesis ◽

Conformationally Locked

Isoxazolineγ-lactams are prepared starting from the regioisomeric cycloadducts of benzonitrile oxide to theN-alkyl 2-azanorbornenes taking advantage of the efficient catalytic oxidation by RuO4. The reduction of the amide groups is easily conducted in the presence of LiAlH4under mild conditions, which allowed for the chemoselective reduction of the amide moiety followed by ring opening to afford the desired conformationally locked isoxazoline-carbocyclic aminols, as valuable intermediates for nucleoside synthesis.

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