ChemInform Abstract: π-Acidic Alkene Ligand Effects in Pd-Catalyzed Cross-Coupling Processes. Exploiting the Interaction of Dibenzylidene Acetone (dba) and Related Ligands with Pd(0) and Pd(II).

ChemInform ◽  
2009 ◽  
Vol 40 (4) ◽  
Author(s):  
Ian J. S. Fairlamb
Keyword(s):  
Cross Coupling ◽  
Ligand Effects ◽  
Coupling Processes

scholarly journals Front Cover: Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ‐BH Platinum Complexes (Eur. J. Inorg. Chem. 35/2021)

2021 ◽  
Vol 2021 (35) ◽  
pp. 3517-3517
Author(s):  
Pablo Ríos ◽  
Francisco José Fernández‐de‐Córdova ◽  
Javier Borge ◽  
Natalia Curado ◽  
Agustí Lledós ◽  
...  
Keyword(s):  
Platinum Complexes ◽  
Front Cover ◽  
Ligand Effects ◽  
Coupling Processes

Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Short Review ◽  
Reductive Coupling ◽  
Recent Developments ◽  
Molecular Complexity ◽  
Metal Catalyzed ◽  
Coupling Processes ◽  
Coupling Strategies

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook

scholarly journals Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes

2019 ◽  
Vol 10 (36) ◽  
pp. 8411-8420 ◽  
Author(s):  
Manuel Hofer ◽  
Teresa de Haro ◽  
Enrique Gómez-Bengoa ◽  
Alexandre Genoux ◽  
Cristina Nevado
Keyword(s):  
Dft Calculations ◽  
Oxidative Coupling ◽  
Cross Coupling ◽  
Reaction Intermediates ◽  
Ligand Effects ◽  
Anionic Ligand

The mechanism of the gold-catalyzed oxidative cross-coupling of arenes and alkynes has been studied in detail combining stoichiometric experiments with putative reaction intermediates and DFT calculations.

Divergent synthesis of arylated pyridin-2(1H)-one derivatives via metal-catalysed cross-coupling processes

Tetrahedron ◽  
2010 ◽  
Vol 66 (32) ◽  
pp. 6138-6149 ◽  
Author(s):  
Jamie S. Siddle ◽  
Andrei S. Batsanov ◽  
Stuart T. Caldwell ◽  
Graeme Cooke ◽  
Martin R. Bryce
Keyword(s):  
Cross Coupling ◽  
Coupling Processes
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