ChemInform Abstract: Facile Synthesis of 2-Bromoindoles by Ligand-Free CuI-Catalyzed Intramolecular Cross-Coupling of gem-Dibromoolefins.

<p>Herein we report a sulfur (IV) mediated cross-coupling for facile synthesis of heteroaromatic substrates. Addition of heteroaryl nucleophiles onto a simple, readily-accessible alkyl sulfinyl (IV) chloride allows formation of a trigonal bipyramidal sulfurane intermediate. Reductive elimination therefrom provides bis-heteroaryl products in a practical and efficient fashion. <br></p>

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Continuous Ligand-Free Suzuki–Miyaura Cross-Coupling Reactions in a Cartridge Flow Reactor Using a Gel-Supported Catalyst

Industrial & Engineering Chemistry Research ◽

10.1021/acs.iecr.1c01531 ◽

2021 ◽

Author(s):

Jeffrey A. Bennett ◽

Bradley A. Davis ◽

Mahdi Ramezani ◽

Jan Genzer ◽

Kirill Efimenko ◽

...

Keyword(s):

Flow Reactor ◽

Supported Catalyst ◽

Cross Coupling ◽

Coupling Reactions ◽

Cross Coupling Reactions ◽

Ligand Free

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Suzuki-Miyaura cross-coupling reaction in water: facile synthesis of (hetero) aryl uracil bases using potassiumorganotrifluoroborates under microwave irradiation.

ChemistrySelect ◽

10.1002/slct.201600943 ◽

2016 ◽

Vol 1 (15) ◽

pp. 4721-4725 ◽

Cited By ~ 9

Author(s):

Bhaskaran Savitha ◽

Ayyiliath M. Sajith ◽

Eeda Koti Reddy ◽

C. S. Ananda Kumar ◽

M. Syed Ali Padusha

Keyword(s):

Microwave Irradiation ◽

Coupling Reaction ◽

Cross Coupling ◽

Facile Synthesis ◽

Cross Coupling Reaction ◽

Reaction In Water

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Facile Synthesis of Cross-Conjugated gem-Disubstituted Trienes via Palladium-Catalyzed Cross-Coupling Protocol of 1,1-Disubstituted 2,4-Diiodo-but-1-ene with Alkenes.

ChemInform ◽

10.1002/chin.200433113 ◽

2004 ◽

Vol 35 (33) ◽

Author(s):

Min Shi ◽

Li-Xiong Shao

Keyword(s):

Cross Coupling ◽

Facile Synthesis ◽

Palladium Catalyzed

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ChemInform Abstract: Improved Microwave-Assisted Ligand-Free Suzuki-Miyaura Cross-Coupling of 5-Iodo-2′-deoxyuridine in Pure Water.

ChemInform ◽

10.1002/chin.201348202 ◽

2013 ◽

Vol 44 (48) ◽

pp. no-no

Author(s):

Shawn Gallagher-Duval ◽

Gwenaelle Herve ◽

Guillaume Sartori ◽

Gerald Enderlin ◽

Christophe Len

Keyword(s):

Pure Water ◽

Cross Coupling ◽

Microwave Assisted ◽

Ligand Free

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Self‐Assembled Multilayer‐Stabilized Nickel Nanoparticle Catalyst for Ligand‐Free Cross‐Coupling Reactions: in situ Metal Nanoparticle and Nanospace Simultaneous Organization

Advanced Synthesis & Catalysis ◽

10.1002/adsc.201600024 ◽

2016 ◽

Vol 358 (15) ◽

pp. 2449-2459 ◽

Cited By ~ 8

Author(s):

Naoyuki Hoshiya ◽

Katsumasa Fujiki ◽

Takahisa Taniguchi ◽

Tetsuo Honma ◽

Yusuke Tamenori ◽

...

Keyword(s):

Cross Coupling ◽

Metal Nanoparticle ◽

Coupling Reactions ◽

Nickel Nanoparticle ◽

Cross Coupling Reactions ◽

Ligand Free ◽

Self Assembled ◽

Nanoparticle Catalyst

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ChemInform Abstract: In situ Generation of Palladium Nanoparticles: Ligand-Free Palladium Catalyzed Ultrafast Suzuki-Miyaura Cross-Coupling Reaction in Aqueous Phase at Room Temperature.

ChemInform ◽

10.1002/chin.201148081 ◽

2011 ◽

Vol 42 (48) ◽

pp. no-no

Author(s):

Zhengyin Du ◽

Wanwei Zhou ◽

Fen Wang ◽

Jin-Xian Wang

Keyword(s):

Aqueous Phase ◽

Palladium Nanoparticles ◽

Room Temperature ◽

Coupling Reaction ◽

Cross Coupling ◽

Cross Coupling Reaction ◽

Ligand Free ◽

Palladium Catalyzed ◽

In Situ Generation

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Novel and facile synthesis of 1-benzazepines via copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling

Chemical Communications ◽

10.1039/c7cc07027f ◽

2017 ◽

Vol 53 (90) ◽

pp. 12229-12232 ◽

Cited By ~ 22

Author(s):

Rui Wang ◽

Ruo-Xing Jin ◽

Zi-Yang Qin ◽

Kang-Jie Bian ◽

Xi-Sheng Wang

Keyword(s):

Cross Coupling ◽

Facile Synthesis ◽

Synthetic Strategy

A novel synthetic strategy for the facile construction of 1-benzazepines has been developedviacopper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling.

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