ChemInform Abstract: Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.

ChemInform ◽  
2011 ◽  
Vol 42 (37) ◽  
pp. no-no
Author(s):  
Kazumi Okuro ◽  
Joanna Gurnham ◽  
Howard Alper
Keyword(s):  
Rhodium Complex

Mechanisms of Catalysis in Confined Spaces: Hydrogenation of Norbornadiene with a Rhodium Complex included in a Self-Folding Cavitand

2013 ◽  
Vol 17 (14) ◽  
pp. 1499-1506 ◽  
Author(s):  
Alex Hamilton ◽  
Michael Gicquel ◽  
Pablo Ballester ◽  
Carles Bo
Keyword(s):  
Rhodium Complex ◽  
Confined Spaces

Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene–Rhodium Complex

2005 ◽  
Vol 34 (11) ◽  
pp. 1480-1481 ◽  
Author(s):  
Tamio Hayashi ◽  
Norihito Tokunaga ◽  
Kazuhiro Okamoto ◽  
Ryo Shintani
Keyword(s):  
Rhodium Complex ◽  
Arylboronic Acids ◽  
Unsaturated Aldehydes

scholarly journals Metallkomplexe in Anorganischen Matrices, 5 [1] / Metal Complexes in Inorganic Matrices, 5 [1]

1991 ◽  
Vol 46 (6) ◽  
pp. 783-788 ◽  
Author(s):  
Christian Egger ◽  
Ulrich Schubert
Keyword(s):  
Acetic Acid ◽  
Metal Complexes ◽  
Phenylacetic Acid ◽  
Sol Gel ◽  
Rhodium Complex ◽  
Gel Processing ◽  
Inorganic Matrices

A heterogenized rhodium complex, prepared by sol-gel processing of Rh(CO)Cl[PPh2CH2CH2Si(OEt)3]2 and Si(OEt)4, is shown to catalyze the conversion of the silanes H4-nSiPh„ (n = 1 - 3) or (HMe2Si)2O to (poly)siloxanes by air or water. Using THF as a solvent, the silanoles Ph3SiOH or Ph2Si(OH)2 are obtained instead. The reaction of phenylacetic acid or acetic acid with HSiPh3 to give silyl esters is catalyzed by the same compound.

ChemInform Abstract: Microwave-Assisted Rhodium-Complex-Catalyzed Cascade Decarbonylation and Asymmetric Pauson-Khand-Type Cyclizations.

ChemInform ◽  
2008 ◽  
Vol 39 (44) ◽  
Author(s):  
Hang Wai Lee ◽  
Lai Na Lee ◽  
Albert S. C. Chan ◽  
Fuk Yee Kwong
Keyword(s):  
Rhodium Complex ◽  
Microwave Assisted

The reaction of [Rh(CO)2Cl]2 with hexafluorobut-2-yne

1978 ◽  
Vol 31 (3) ◽  
pp. 661 ◽  
Author(s):  
RS Dickson ◽  
SH Johnson
Keyword(s):  
Molecular Structure ◽  
Approximate Formula ◽  
Chemical Properties ◽  
Extensive Study ◽  
Rhodium Complex ◽  
And Chemical Properties

The reaction of [Rh(CO)2Cl]2 with CF3C≡CCF3 gives a fluorocarbon-rhodium complex of approximate formula [RhCl(CO)2 or 3(C4F6)]n,xH2O,yC6H6. The complex is an intermediate in the formation of tetrakis(trifluoromethyl)cyclopentadienone from CF3C≡CCF3 and CO in the presence of[Rh(CO)2Cl]2. The molecular structure of the complex remains obscure despite extensive study of its spectroscopic and chemical properties. The major products formed in the reactions of the complex with σ-cyclopentadienylthallium and with triphenylphosphine are (η- C5H5)2Rh2(CO)2(CF3C2CF3)and Rh(CO)Cl(PPh3)2 respectively.

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