Intramolecular SNAr reactions as a route to complexes of hybrid cyclopentadienyl–phosphine ligands: synthesis of a rhodium complex of the first η5,η1,η1-cyclopentadienyl–phosphine–thioether ligand

2001 ◽  
pp. 512-514 ◽  
Author(s):  
Ronan M. Bellabarba ◽  
Mark Nieuwenhuyzen ◽  
Graham C. Saunders
Keyword(s):  
Phosphine Ligands ◽  
Rhodium Complex

Mechanisms of Catalysis in Confined Spaces: Hydrogenation of Norbornadiene with a Rhodium Complex included in a Self-Folding Cavitand

2013 ◽  
Vol 17 (14) ◽  
pp. 1499-1506 ◽  
Author(s):  
Alex Hamilton ◽  
Michael Gicquel ◽  
Pablo Ballester ◽  
Carles Bo
Keyword(s):  
Rhodium Complex ◽  
Confined Spaces

Ruthenium(II) Complexes with N-Heterocyclic Carbene-Phosphine Ligands for the N-Alkylation of Amines with Alcohols

2021 ◽  
Author(s):  
Ming Huang ◽  
Yinwu Li ◽  
Xiao-Bing Lan ◽  
Jiahao Liu ◽  
Cunyuan Zhao ◽  
...  
Keyword(s):  
Metal Hydride ◽  
Phosphine Ligands ◽  
Hydride Complexes ◽  
Borrowing Hydrogen ◽  
Hydrogen Autotransfer

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols...

scholarly journals Efficient photorelease of carbon monoxide from a luminescent tricarbonyl rhenium(i) complex incorporating pyridyl-1,2,4-triazole and phosphine ligands

2021 ◽  
Author(s):  
Ángel D. Hernández Mejías ◽  
Alexandre Poirot ◽  
Meriem Rmili ◽  
Nadine Leygue ◽  
Mariusz Wolff ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Colour Change ◽  
Phosphine Ligands

In this new Re(i) PhotoCORM, the efficient photoproduction of carbon monoxide is visualized through a strong colour change of the emitted phosphorescence.

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