ChemInform Abstract: Design and Development of Photoanodes for Water-Splitting Dye-Sensitized Photoelectrochemical Cells

ChemInform ◽  
2013 ◽  
Vol 44 (24) ◽  
pp. no-no
Author(s):  
John R. Swierk ◽  
Thomas E. Mallouk
2017 ◽  
Vol 46 (2) ◽  
pp. 559-559 ◽  
Author(s):  
John R. Swierk ◽  
Thomas E. Mallouk

Correction for ‘Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells’ by John R. Swierk et al., Chem. Soc. Rev., 2013, 42, 2357–2387.


2015 ◽  
Vol 112 (6) ◽  
pp. 1681-1686 ◽  
Author(s):  
John R. Swierk ◽  
Dalvin D. Méndez-Hernández ◽  
Nicholas S. McCool ◽  
Paul Liddell ◽  
Yuichi Terazono ◽  
...  

Solar fuel generation requires the efficient capture and conversion of visible light. In both natural and artificial systems, molecular sensitizers can be tuned to capture, convert, and transfer visible light energy. We demonstrate that a series of metal-free porphyrins can drive photoelectrochemical water splitting under broadband and red light (λ > 590 nm) illumination in a dye-sensitized TiO2 solar cell. We report the synthesis, spectral, and electrochemical properties of the sensitizers. Despite slow recombination of photoinjected electrons with oxidized porphyrins, photocurrents are low because of low injection yields and slow electron self-exchange between oxidized porphyrins. The free-base porphyrins are stable under conditions of water photoelectrolysis and in some cases photovoltages in excess of 1 V are observed.


2015 ◽  
Vol 8 (3) ◽  
pp. 760-775 ◽  
Author(s):  
Ze Yu ◽  
Fei Li ◽  
Licheng Sun

Dye-sensitized photoelectrochemical cells based on molecular components represent promising approaches to generate hydrogenviasolar-driven water splitting.


2014 ◽  
Vol 118 (30) ◽  
pp. 17046-17053 ◽  
Author(s):  
John R. Swierk ◽  
Nicholas S. McCool ◽  
Timothy P. Saunders ◽  
Greg D. Barber ◽  
Megan E. Strayer ◽  
...  

2018 ◽  
Vol 5 (17) ◽  
pp. 2395-2402 ◽  
Author(s):  
Norberto Manfredi ◽  
Chiara Liliana Boldrini ◽  
Alessandro Abbotto

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