ChemInform Abstract: Tandem Nucleophilic Addition-Oppenauer Oxidation of Aromatic Aldehydes to Aryl Ketones with Triorganoaluminum Reagents.

ChemInform ◽  
2013 ◽  
Vol 44 (42) ◽  
pp. no-no
Author(s):  
Ying Fu ◽  
Yanshou Yang ◽  
Helmut M. Huegel ◽  
Zhengyin Du ◽  
Kehu Wang ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Aromatic Aldehydes ◽  
Aryl Ketones ◽  
Oppenauer Oxidation

Tandem nucleophilic addition–Oppenauer oxidation of aromatic aldehydes to aryl ketones with triorganoaluminium reagents

2013 ◽  
Vol 11 (27) ◽  
pp. 4429 ◽  
Author(s):  
Ying Fu ◽  
Yanshou Yang ◽  
Helmut M. Hügel ◽  
Zhengyin Du ◽  
Kehu Wang ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Aromatic Aldehydes ◽  
Aryl Ketones ◽  
Oppenauer Oxidation

Magnesium salt promoted tandem nucleophilic addition–Oppenauer oxidation of aldehydes with organozinc reagents

2016 ◽  
Vol 14 (41) ◽  
pp. 9720-9724 ◽  
Author(s):  
Ying Fu ◽  
Xing Ling Zhao ◽  
Hulmet Hügel ◽  
Danfeng Huang ◽  
Zhengyin Du ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Aromatic Aldehydes ◽  
Magnesium Salt ◽  
Facile Synthesis ◽  
Aromatic Ketones ◽  
Oppenauer Oxidation ◽  
Organozinc Reagents

A facile synthesis of aromatic ketones via tandem nucleophilic addition–Oppenauer oxidation of aromatic aldehydes with organozinc reagents was demonstrated. Magnesium salt in situ generated via organozinc formation is a powerful promotor for this transformation.

scholarly journals Convenient One-Pot Synthesis of Allylsilanes from Enolizable Ketones

SynOpen ◽  
2019 ◽  
Vol 03 (04) ◽  
pp. 138-141
Author(s):  
Man Lung D. Kwan ◽  
Paul R. Challen ◽  
Quynh D.-D. Tran
Keyword(s):  
Nucleophilic Addition ◽  
Slight Modification ◽  
Second Step ◽  
One Pot ◽  
One Pot Synthesis ◽  
Aryl Ketones

A convenient one-pot synthesis of allylsilanes from enolizable methyl aryl ketones has been developed. The first step involves nucleophilic addition of the trimethylsilylmethyl group to ketones using the alkylation method developed by Ishihara with slight modification to generate the corresponding β-silylalkoxides. The second step entails addition of diisobutylaluminum chloride and heating at about 130 °C overnight to afford allylsilanes in fair yields.

The NHCs-mediated cross-coupling of aromatic aldehydes with benzyl halides: synthesis of α-aryl ketones

2010 ◽  
Vol 51 (27) ◽  
pp. 3571-3574 ◽  
Author(s):  
Lu Lin ◽  
Yi Li ◽  
Wenting Du ◽  
Wei-Ping Deng
Keyword(s):  
Cross Coupling ◽  
Aromatic Aldehydes ◽  
Aryl Ketones ◽  
Benzyl Halides

scholarly journals Intramolecular Nucleophilic Addition of Vinylpalladiums to Aryl Ketones [J. Am. Chem. Soc.1999,121, 3545−3546].

1999 ◽  
Vol 121 (40) ◽  
pp. 9485-9485 ◽  
Author(s):  
Long Gyo Quan ◽  
Vladimir Gevorgyan ◽  
Yoshinori Yamamoto
Keyword(s):  
Nucleophilic Addition ◽  
Aryl Ketones
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