ChemInform Abstract: System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes.

ChemInform ◽  
2015 ◽  
Vol 46 (18) ◽  
pp. no-no
Author(s):  
Eran Fogler ◽  
Jai Anand Garg ◽  
Peng Hu ◽  
Gregory Leitus ◽  
Linda J. W. Shimon ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Abstract System ◽  
Catalytically Active ◽  
Metal Ligand

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

2014 ◽  
Vol 20 (48) ◽  
pp. 15727-15731 ◽  
Author(s):  
Eran Fogler ◽  
Jai Anand Garg ◽  
Peng Hu ◽  
Gregory Leitus ◽  
Linda J. W. Shimon ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Catalytically Active ◽  
Metal Ligand

scholarly journals Capable Cross-links: Polymersomes Reinforced with Catalytically Active Metal–Ligand Bonds

2015 ◽  
Vol 27 (13) ◽  
pp. 4808-4813 ◽  
Author(s):  
Ian M. Henderson ◽  
Hope A. Quintana ◽  
Julio A. Martinez ◽  
Walter F. Paxton
Keyword(s):  
Active Metal ◽  
Catalytically Active ◽  
Cross Links ◽  
Metal Ligand

B–H Bond Cleavage via Metal–Ligand Cooperation by Dearomatized Ruthenium Pincer Complexes

2014 ◽  
Vol 33 (14) ◽  
pp. 3716-3726 ◽  
Author(s):  
Aviel Anaby ◽  
Burkhard Butschke ◽  
Yehoshoa Ben-David ◽  
Linda J. W. Shimon ◽  
Gregory Leitus ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Pincer Complexes ◽  
Metal Ligand

scholarly journals Hydration of nitriles using a metal–ligand cooperative ruthenium pincer catalyst

2019 ◽  
Vol 10 (45) ◽  
pp. 10647-10652 ◽  
Author(s):  
Beibei Guo ◽  
Johannes G. de Vries ◽  
Edwin Otten
Keyword(s):  
Pincer Complexes ◽  
Aromatic Nitriles ◽  
Mild Conditions ◽  
Metal Ligand

The hydration of a broad range of aliphatic and (hetero)aromatic nitriles is reported via catalysis by metal–ligand cooperative Ru pincer complexes under very mild conditions.

O2 Activation by Metal–Ligand Cooperation with IrI PNP Pincer Complexes

2015 ◽  
Vol 137 (14) ◽  
pp. 4634-4637 ◽  
Author(s):  
Moran Feller ◽  
Eyal Ben-Ari ◽  
Yael Diskin-Posner ◽  
Raanan Carmieli ◽  
Lev Weiner ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
O2 Activation ◽  
Metal Ligand

scholarly journals Front Cover: Metal‐ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes (14/2021)

2021 ◽  
Vol 647 (14) ◽  
pp. 1397-1397
Author(s):  
Annika M. Krieger ◽  
Vivek Sinha ◽  
Adarsh V. Kalikadien ◽  
Evgeny A. Pidko
Keyword(s):  
Pincer Complexes ◽  
Front Cover ◽  
Cooperative Activation ◽  
Metal Ligand

scholarly journals Palladium(II) pincer complexes of α-amino acids: towards the synthesis of catalytically active artificial peptides

2002 ◽  
Vol 43 (21) ◽  
pp. 3895-3898 ◽  
Author(s):  
Gabriela Guillena ◽  
Gema Rodrı́guez ◽  
Gerard van Koten
Keyword(s):  
Amino Acids ◽  
Pincer Complexes ◽  
Catalytically Active

scholarly journals Bulky PNP Ligands Blocking Metal-Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation

2021 ◽  
Author(s):  
Shubham Deolka ◽  
Robert R. Fayzullin ◽  
Eugene Khaskin
Keyword(s):  
Ru Complex ◽  
Catalytically Active ◽  
Ru Complexes ◽  
Alcohol Dehydrogenation ◽  
Complex Chemistry ◽  
Acceptorless Alcohol Dehydrogenation ◽  
Cis And Trans ◽  
Metal Ligand

We synthesized two 4Me-PNP ligands which block metal-ligand cooperation (MLC) with the Ru center and compared their Ru complex chemistry to their two traditional analogues used in acceptorless alcohol dehydrogenation catalysis. The corresponding 4Me-PNP complexes, which do not undergo dearomatization upon addition of base, allowed us to obtain rare, albeit unstable, 16 electron mono CO Ru(0) complexes. Reactivity with CO and H<sub>2</sub> allows for stabilization and extensive characterization of bis CO Ru(0) 18 electron and Ru(II) cis and trans dihydride species that were also shown to be capable of C(sp<sup>2</sup>)-H activation. Reactivity and catalysis are contrasted to non-methylated Ru(II) species, showing that an MLC pathway is not necessary, with dramatic differences in outcomes during catalysis between <sup>i</sup>Pr and <sup>t</sup>Bu PNP complexes within each of the 4Me and non-methylated backbone PNP series being observed. Unusual intermediates are characterized in one of the new and one of the traditional complexes, and a common catalysis deactivation pathway was identified.

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