O2 Activation by Metal–Ligand Cooperation with IrI PNP Pincer Complexes

2015 ◽  
Vol 137 (14) ◽  
pp. 4634-4637 ◽  
Author(s):  
Moran Feller ◽  
Eyal Ben-Ari ◽  
Yael Diskin-Posner ◽  
Raanan Carmieli ◽  
Lev Weiner ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
O2 Activation ◽  
Metal Ligand

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

2014 ◽  
Vol 20 (48) ◽  
pp. 15727-15731 ◽  
Author(s):  
Eran Fogler ◽  
Jai Anand Garg ◽  
Peng Hu ◽  
Gregory Leitus ◽  
Linda J. W. Shimon ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Catalytically Active ◽  
Metal Ligand

B–H Bond Cleavage via Metal–Ligand Cooperation by Dearomatized Ruthenium Pincer Complexes

2014 ◽  
Vol 33 (14) ◽  
pp. 3716-3726 ◽  
Author(s):  
Aviel Anaby ◽  
Burkhard Butschke ◽  
Yehoshoa Ben-David ◽  
Linda J. W. Shimon ◽  
Gregory Leitus ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Pincer Complexes ◽  
Metal Ligand

scholarly journals Hydration of nitriles using a metal–ligand cooperative ruthenium pincer catalyst

2019 ◽  
Vol 10 (45) ◽  
pp. 10647-10652 ◽  
Author(s):  
Beibei Guo ◽  
Johannes G. de Vries ◽  
Edwin Otten
Keyword(s):  
Pincer Complexes ◽  
Aromatic Nitriles ◽  
Mild Conditions ◽  
Metal Ligand

The hydration of a broad range of aliphatic and (hetero)aromatic nitriles is reported via catalysis by metal–ligand cooperative Ru pincer complexes under very mild conditions.

ChemInform Abstract: System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes.

ChemInform ◽  
2015 ◽  
Vol 46 (18) ◽  
pp. no-no
Author(s):  
Eran Fogler ◽  
Jai Anand Garg ◽  
Peng Hu ◽  
Gregory Leitus ◽  
Linda J. W. Shimon ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Abstract System ◽  
Catalytically Active ◽  
Metal Ligand

scholarly journals Front Cover: Metal‐ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes (14/2021)

2021 ◽  
Vol 647 (14) ◽  
pp. 1397-1397
Author(s):  
Annika M. Krieger ◽  
Vivek Sinha ◽  
Adarsh V. Kalikadien ◽  
Evgeny A. Pidko
Keyword(s):  
Pincer Complexes ◽  
Front Cover ◽  
Cooperative Activation ◽  
Metal Ligand

scholarly journals Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2

2018 ◽  
Vol 37 (14) ◽  
pp. 2217-2221 ◽  
Author(s):  
Dror Oren ◽  
Yael Diskin-Posner ◽  
Liat Avram ◽  
Moran Feller ◽  
David Milstein
Keyword(s):  
Pincer Complexes ◽  
Metal Ligand

scholarly journals Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation

2015 ◽  
Vol 373 (2037) ◽  
pp. 20140189 ◽  
Author(s):  
David Milstein
Keyword(s):  
Bond Activation ◽  
Short Review ◽  
Catalytic Reactions ◽  
Pincer Complexes ◽  
Chemical Bonds ◽  
Single Bond ◽  
Metal Centre ◽  
Pincer Ligand ◽  
Mechanistic Insight ◽  
Metal Ligand

Metal–ligand cooperation (MLC) plays an important role in bond activation processes, enabling many chemical and biological catalytic reactions. A recent new mode of activation of chemical bonds involves ligand aromatization–dearomatization processes in pyridine-based pincer complexes in which chemical bonds are broken reversibly across the metal centre and the pincer-ligand arm, leading to new bond-making and -breaking processes, and new catalysis. In this short review, such processes are briefly exemplified in the activation of C–H, H–H, O–H, N–H and B–H bonds, and mechanistic insight is provided. This new bond activation mode has led to the development of various catalytic reactions, mainly based on alcohols and amines, and to a stepwise approach to thermal H 2 and light-induced O 2 liberation from water.

Dinuclear Helicate or Mononuclear Pincer Lanthanide Complexes from One Ligand: Stereo-Controlled Assembly and Catalysis

2021 ◽  
Author(s):  
Ran Chen ◽  
Qian-Qian Yan ◽  
Shao-Jun Hu ◽  
Xiao-Qing Guo ◽  
Li-Xuan Cai ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Pincer Complexes ◽  
Controlled Assembly ◽  
Ligand Ratio ◽  
Metal Ligand

By varying the metal/ligand ratio, either dinuclear triple helicates (ΛΛ/ΔΔ-La2LR/S 3) or mononuclear pincer complexes (Λ/Δ-LaLR/S) can be stereo-selectively obtained from the same chiral bistridentate ligand (LR/S). Due to the...

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