Determination of reactivity ratios for acrylic acid and its dimer from classical parameter estimation and Bayesian approach

2021 ◽  
Author(s):  
Klaus‐Dieter Hungenberg ◽  
Christian Schwede ◽  
Michael Wulkow ◽  
Niklas Wulkow
Keyword(s):  
Parameter Estimation ◽  
Acrylic Acid ◽  
Bayesian Approach ◽  
Reactivity Ratios ◽  
Classical Parameter

Percipitation copolymerization of acrylamide and acrylic acid: Determination of reactivity ratio by various methods

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Sedigheh Nazaripour ◽  
Mehdi Rafizadeh ◽  
Hosein Bouhendi
Keyword(s):  
Hydrogen Bonding ◽  
Acrylic Acid ◽  
Reactivity Ratio ◽  
Copolymer Composition ◽  
Reactivity Ratios ◽  
Nonlinear Method ◽  
Monomer Reactivity Ratios ◽  
Polymerization Method ◽  
Acid Determination

AbstractCopolymers of acrylamide ( AM ) and acrylic acid ( AA) were prepared by precipitation polymerization method at 65 °C in the ethyl acetate as solvent. Copolymer composition was determined by elemental analysis. Monomer reactivity ratios were determined in low conversions. Mayo-Lewis, Finemann-Ross, Inverted Finemann-Ross, Ezrielev-Brokhina-Roskin, Kelen-Tudos, Extended Kelen-Tudos and Mao-Huglin methods, as linear methods, and Tidwell-Mortimer, as nonlinear method, were applied to calculate rAM and rAA r reactivity ratios. Monomer reactivity ratios of AM and AA were obtained 0.46 and 0.28, respectively. Comparing of reactivity ratios of AM and AA in this work by other solvents showed that hydrogen bonding and ionic strength are important parameters that can affect the reactivity ratios of monomers. Moreover, microstructure of copolymers was determined using reactivity ratios and conditional probability based on the kinetic model for free-radical polymerization.

Determination of reactivity ratios for the copolymerization of poly(acrylic acid-co-itaconic acid)

2016 ◽  
Vol 133 (40) ◽  
Author(s):  
Shidan Cummings ◽  
Yujie Zhang ◽  
Niousha Kazemi ◽  
Alexander Penlidis ◽  
Marc A. Dubé
Keyword(s):  
Acrylic Acid ◽  
Itaconic Acid ◽  
Reactivity Ratios ◽  
Poly Acrylic Acid

Photo-induced controlled/living copolymerization of styrene and acrylic acid and determination of reactivity ratios

2014 ◽  
Vol 23 (10) ◽  
pp. 819-826 ◽  
Author(s):  
Guo-Xiang Wang ◽  
Mang Lu ◽  
Chan-An Yang ◽  
Zhao-Hui Hou ◽  
Yong Gao ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Reactivity Ratios

Effect of ionic strength on the reactivity ratios of acrylamide/acrylic acid (sodium acrylate) copolymerization

2014 ◽  
Vol 131 (20) ◽  
pp. n/a-n/a ◽  
Author(s):  
Marzieh Riahinezhad ◽  
Niousha Kazemi ◽  
Neil McManus ◽  
Alexander Penlidis
Keyword(s):  
Ionic Strength ◽  
Acrylic Acid ◽  
Sodium Acrylate ◽  
Reactivity Ratios
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