scholarly journals NMR Lineshapes and Scalar Relaxation of the Water-Endofullerene H2 17 O@C60

ChemPhysChem ◽  
2018 ◽  
Vol 19 (3) ◽  
pp. 251-255 ◽  
Author(s):  
Stuart James Elliott ◽  
Christian Bengs ◽  
Karel Kouril ◽  
Benno Meier ◽  
Shamim Alom ◽  
...  
Keyword(s):  
1973 ◽  
Vol 28 (10) ◽  
pp. 1731-1732
Author(s):  
M. Žaucer ◽  
J. Perko ◽  
F. Jagodic ◽  
A. Ažman

14N and H spin-lattice relaxations have been measured. Various contributions to the protons spin-lattice relaxations are determined. The spin-rotation and the scalar relaxation, through quadrupole relaxation of N. contribute considerably.


1981 ◽  
Vol 42 (1) ◽  
pp. 141-146 ◽  
Author(s):  
A Briguet ◽  
J.C Duplan ◽  
J Delmau
Keyword(s):  

1986 ◽  
Vol 41 (5) ◽  
pp. 553-559 ◽  
Author(s):  
Alfred Schmidpeter ◽  
Bernd Wrackmeyer

A systematic natural abundance 15N NMR study of diazaphospholes is presented for the first time, giving accurate values for chemical shifts, δN , and coupling constants J(31P15N), J(15N1H ). 14N NMR spectra can be used to predict the magnitude of 1J( 31P14N) if the broadening of the 31P resonance by scalar relaxation is known. The relaxation behaviour of the 14N nuclei corresponds to that found in azoles indicating a comparable electronic ground state structure. The comparison of the chemical shifts, δN, in the diazaphospholes with δN of corresponding triazoles reveals differences which can be traced to the N-P σ-bonds and to the influence o f the phosphorus atom on the π-system. A linear correlation δN/δP exists coordinate nitrogen and phosphorus, respectively.


2019 ◽  
Vol 298 ◽  
pp. 101-106 ◽  
Author(s):  
Michael C.D. Tayler ◽  
Lynn F. Gladden

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