Metal‐Organic Frameworks for Hydrogen Energy Applications: Advances and Challenges

ChemPhysChem ◽  
2019 ◽  
Vol 20 (10) ◽  
pp. 1177-1215 ◽  
Author(s):  
Vasudeva Rao Bakuru ◽  
Marilyn Esclance DMello ◽  
Suresh Babu Kalidindi
Keyword(s):  
Metal Organic Frameworks ◽  
Hydrogen Energy ◽  
Energy Applications ◽  
Metal Organic

scholarly journals Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

AbstractDeveloping high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36 mV at a current density of 10 mA cm−2 in 1 M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

Metal-Organic Frameworks Catalyst for Energy Applications

2021 ◽  
pp. 151-170
Author(s):  
Deepa Rajwar ◽  
Gayatri Chauhan ◽  
Alok Kumar
Keyword(s):  
Metal Organic Frameworks ◽  
Energy Applications ◽  
Metal Organic

scholarly journals Electrocatalytic Metal-Organic Frameworks for Energy Applications

ChemSusChem ◽  
2017 ◽  
Vol 10 (22) ◽  
pp. 4374-4392 ◽  
Author(s):  
Courtney A. Downes ◽  
Smaranda C. Marinescu
Keyword(s):  
Metal Organic Frameworks ◽  
Energy Applications ◽  
Metal Organic

Synthesis and energy applications of metal organic frameworks

2015 ◽  
Vol 22 (2) ◽  
pp. 413-424 ◽  
Author(s):  
Pawan Kumar ◽  
Vasudha Bansal ◽  
Akash Deep ◽  
Ki-Hyun Kim
Keyword(s):  
Metal Organic Frameworks ◽  
Energy Applications ◽  
Metal Organic

Heat-treatment of metal–organic frameworks for green energy applications

CrystEngComm ◽  
2015 ◽  
Vol 17 (1) ◽  
pp. 10-22 ◽  
Author(s):  
Lacey Lux ◽  
Kia Williams ◽  
Shengqian Ma
Keyword(s):  
Heat Treatment ◽  
Metal Organic Frameworks ◽  
Green Energy ◽  
Energy Applications ◽  
Metal Organic

On the potential for nanoscale metal–organic frameworks for energy applications

2019 ◽  
Vol 7 (38) ◽  
pp. 21545-21576 ◽  
Author(s):  
Seher Kuyuldar ◽  
Douglas T. Genna ◽  
Clemens Burda
Keyword(s):  
Fuel Cells ◽  
Solar Energy ◽  
Energy Conversion ◽  
Metal Organic Frameworks ◽  
Solar Energy Conversion ◽  
Energy Applications ◽  
Energy Conversion Systems ◽  
Metal Organic

Nanoscale metal organic frameworks offer unique advantages for the development of materials for solar energy conversion systems, supercapacitors, batteries and fuel cells.

Metal–organic frameworks as a platform for clean energy applications

EnergyChem ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. 100027 ◽  
Author(s):  
Xinran Li ◽  
Xinchun Yang ◽  
Huaiguo Xue ◽  
Huan Pang ◽  
Qiang Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Energy Applications ◽  
Metal Organic

State of the art developments and prospects of metal-organic frameworks for energy applications

2021 ◽  
Author(s):  
Mohd Zeeshan ◽  
M. Shahid
Keyword(s):  
State Of The Art ◽  
Metal Organic Frameworks ◽  
Energy Applications ◽  
Energy Technologies ◽  
Metal Organic ◽  
And Storage

The progress of cleaner and ecological transformation and storage of energy technologies to combat effluence or pollution and the impending energy dilemma has recently fascinated the interest of the energy...

Modulating Electronic Structure of Metal-Organic Frameworks by Introducing Atomically Dispersed Ru for Efficient Hydrogen Evolution

2020 ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

Abstract Developing high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction (HER) electrocatalyst (NiRu0.13-BDC, BDC: terephthalic acid) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding HER activity in all pH, especially with a low overpotential of only 36 mV at a current density of 10 mA cm-2 in 1 M phosphate buffered saline (PBS) solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

Sign in / Sign up

Export Citation Format

Share Document