Visible Light Promoted Reversible Sulfide/Iodide Exchange in Fluoroalkyl Sulfides Enabled by Electron Donor‐Acceptor Complex Formation

ChemPhotoChem ◽  
2021 ◽  
Author(s):  
Boris A. van der Worp ◽  
Mikhail D. Kosobokov ◽  
Alexander Dilman
Keyword(s):  
Complex Formation ◽  
Visible Light ◽  
Electron Donor ◽  
Acceptor Complex ◽  
Donor Acceptor

A visible-light-irradiated electron donor-acceptor complex-promoted radical reaction system for the C H perfluoroalkylation of quinolin-4-ols

2019 ◽  
Vol 60 (38) ◽  
pp. 151046 ◽  
Author(s):  
Yunze Li ◽  
Min Rao ◽  
Zhenwei Fan ◽  
Baoyi Nian ◽  
Yaofeng Yuan ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Radical Reaction ◽  
Reaction System ◽  
Acceptor Complex ◽  
Donor Acceptor

scholarly journals Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones

2020 ◽  
Vol 11 (5) ◽  
pp. 1353-1360 ◽  
Author(s):  
Hon Eong Ho ◽  
Angela Pagano ◽  
James A. Rossi-Ashton ◽  
James R. Donald ◽  
Ryan G. Epton ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Intramolecular Charge Transfer ◽  
Thiyl Radical ◽  
Acceptor Complex ◽  
Donor Acceptor ◽  
Radical Generation ◽  
Induced Charge

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols.

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