Mechanistic Insights into Visible-Light-Driven Dearomative Fluoroalkylation Mediated by an Electron Donor–Acceptor Complex

2022 ◽  
Author(s):  
Lishuang Ma ◽  
Wenxu Feng ◽  
Yanyan Xi ◽  
Xuebo Chen ◽  
Xufeng Lin
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Acceptor Complex ◽  
Visible Light Driven ◽  
Donor Acceptor

Visible-Light-Driven Electron Donor–Acceptor Complex Induced Sulfonylation of Diazonium Salts with Sulfinates

2021 ◽  
Author(s):  
Xin Liang ◽  
Yufei Li ◽  
Qing Xia ◽  
Lan Cheng ◽  
Jianbo Guo ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Coupling Reaction ◽  
Diazonium Salts ◽  
Acceptor Complex ◽  
Radical Coupling ◽  
Visible Light Driven ◽  
Donor Acceptor ◽  
Radical Coupling Reaction ◽  
Eda Complex

This work reports an efficient sulfonylation enabled by visible-light-induced radical coupling reaction between phenyl/heterocyclic diazonium salts and sulfinates. Mechanistic experiments disclosed the formation of a versatile electron donor–acceptor (EDA) complex....

A visible-light-irradiated electron donor-acceptor complex-promoted radical reaction system for the C H perfluoroalkylation of quinolin-4-ols

2019 ◽  
Vol 60 (38) ◽  
pp. 151046 ◽  
Author(s):  
Yunze Li ◽  
Min Rao ◽  
Zhenwei Fan ◽  
Baoyi Nian ◽  
Yaofeng Yuan ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Radical Reaction ◽  
Reaction System ◽  
Acceptor Complex ◽  
Donor Acceptor

scholarly journals Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones

2020 ◽  
Vol 11 (5) ◽  
pp. 1353-1360 ◽  
Author(s):  
Hon Eong Ho ◽  
Angela Pagano ◽  
James A. Rossi-Ashton ◽  
James R. Donald ◽  
Ryan G. Epton ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Intramolecular Charge Transfer ◽  
Thiyl Radical ◽  
Acceptor Complex ◽  
Donor Acceptor ◽  
Radical Generation ◽  
Induced Charge

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols.

Visible Light-Driven α-Alkylation of N-Aryl tetrahydroisoquinolines Initiated by Electron Donor–Acceptor Complexes

2020 ◽  
Vol 22 (18) ◽  
pp. 7290-7294 ◽  
Author(s):  
Qing Xia ◽  
Yufei Li ◽  
Xinmin Wang ◽  
Peng Dai ◽  
Hongping Deng ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Visible Light Driven ◽  
Donor Acceptor
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