Superior Performance of Metal-Organic Frameworks over Zeolites as Solid Acid Catalysts in the Prins Reaction: Green Synthesis of Nopol

ChemSusChem ◽  
2013 ◽  
Vol 6 (5) ◽  
pp. 865-871 ◽  
Author(s):  
Maksym Opanasenko ◽  
Amarajothi Dhakshinamoorthy ◽  
Young Kyu Hwang ◽  
Jong-San Chang ◽  
Hermenegildo Garcia ◽  
...  
2010 ◽  
Vol 352 (17) ◽  
pp. 3022-3030 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia

2014 ◽  
Vol 16 (5) ◽  
pp. 2490-2499 ◽  
Author(s):  
Jinzhu Chen ◽  
Kegui Li ◽  
Limin Chen ◽  
Ruliang Liu ◽  
Xing Huang ◽  
...  

Sulfonic acid-functionalized metal–organic frameworks are efficiently used as recyclable solid acid catalysts for the fructose-to-HMF transformation.


2014 ◽  
Vol 4 (11) ◽  
pp. 4065-4074 ◽  
Author(s):  
Vijaykumar S. Marakatti ◽  
Anand B. Halgeri ◽  
Ganapati V. Shanbhag

The application of metal ion-exchanged zeolites as highly active and selective catalysts for the synthesis of nopol from the Prins reaction of β-pinene is reported.


Author(s):  
Yutian Qin ◽  
Jun Guo ◽  
Meiting Zhao

AbstractBiomass is a green and producible source of energy and chemicals. Hence, developing high-efficiency catalysts for biomass utilization and transformation is urgently demanded. Metal–organic framework (MOF)-based solid acid materials have been considered as promising catalysts in biomass transformation. In this review, we first introduce the genre of Lewis acid and Brønsted acid sites commonly generated in MOFs or MOF-based composites. Then, the methods for the generation and adjustment of corresponding acid sites are overviewed. Next, the catalytic applications of MOF-based solid acid materials in various biomass transformation reactions are summarized and discussed. Furthermore, based on our personal insights, the challenges and outlook on the future development of MOF-based solid acid catalysts are provided. We hope that this review will provide an instructive roadmap for future research on MOFs and MOF-based composites for biomass transformation.


2018 ◽  
Vol 33 (23) ◽  
pp. 3946-3952 ◽  
Author(s):  
Xu Zhang ◽  
Qiuyu Fan ◽  
He Yang

Abstract


2008 ◽  
Vol 5 (3) ◽  
pp. 467-472 ◽  
Author(s):  
Muthuraj Esther Leena Preethi ◽  
Shanmugam Revathi ◽  
Thiripuranthagan Sivakumar

Syntheses of benzylated aromatics like diphenylmethane and its derivatives by the condensation of benzene or toluene oro-xylene with benzylchloride or 4-methylbenzylchloride in the presence of a catalytic amount of various iron loaded mesoporous solid acid catalysts such as Fe/Al-MCM-41 (Si/Al=25), Fe/Al-MCM-41 (Si/Al=50) and Fe/Al-MCM-41 (Si/Al=100) are reported.


RSC Advances ◽  
2015 ◽  
Vol 5 (19) ◽  
pp. 14286-14293 ◽  
Author(s):  
Vijaykumar S. Marakatti ◽  
Anand B. Halgeri

The application of metal ion-exchanged zeolites as highly efficient catalysts for the synthesis of glycerol carbonate from glycerol carbonylation is reported.


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