High Shear Homogenization of Lignin to Nanolignin and Thermal Stability of Nanolignin-Polyvinyl Alcohol Blends

ChemSusChem ◽  
2014 ◽  
Vol 7 (12) ◽  
pp. 3513-3520 ◽  
Author(s):  
Sandeep S. Nair ◽  
Sudhir Sharma ◽  
Yunqiao Pu ◽  
Qining Sun ◽  
Shaobo Pan ◽  
...  
2015 ◽  
Vol 130 ◽  
pp. 440-447 ◽  
Author(s):  
Marina I. Voronova ◽  
Oleg V. Surov ◽  
Sabir S. Guseinov ◽  
Vladimir P. Barannikov ◽  
Anatoly G. Zakharov

2018 ◽  
Vol 25 (5) ◽  
pp. 975-982 ◽  
Author(s):  
Alireza Khoshkbar Sadeghi ◽  
Maryam Farbodi

AbstractIn the present research, polyaniline is used as a conducting polymer and polyvinyl alcohol is also used as a biopolymer, because of its mechanical properties and suitable processability. Also, silver nanoparticles are considered as a reinforcing agent of thermal stability, mechanical and antibacterial properties to prepare polyaniline-polyvinyl alcohol-silver nanocomposite. The synthesis of polyaniline-polyvinyl alcohol composite and polyaniline-polyvinyl alcohol-silver nanocomposite is performed through addition of polyaniline and silver in polyvinyl alcohol solution. In order to review thermal, mechanical and antibacterial properties of synthesized composite and nanocomposites, components with different weight rates are used. The obtained results from thermogravimetric analysis (TGA) tests also indicate promotion of thermal stability of polyaniline-polyvinyl alcohol-silver nanocomposite compared with pure polyvinyl alcohol in temperatures above 400°C. The results of Fourier-transform infrared (FTIR) spectroscopy revealed the presence of polyaniline, polyvinyl alcohol and silver in the structure of polyaniline-polyvinyl alcohol-silver triple nanocomposite film. The obtained results from a review of antibacterial properties showed that polyaniline-polyvinyl alcohol-silver nanocomposites have antibacterial effects on two different types of Gram-positive and Gram-negative bacteria. The obtained results from a review of mechanical properties of nanocomposites showed that the greatest value of tensile strength (13.8 MPa) belonged to polyaniline-polyvinyl alcohol-silver (88%/9%/3% w/w) nanocomposites. Therefore, this is determined as an optimal triple nanocomposite. In addition, scanning electron microscopy (SEM) coupled with an energy dispersive X-ray (EDX) system was used to characterize the composition and structure of polyaniline-polyvinyl alcohol-silver nanocomposite film.


Particuology ◽  
2015 ◽  
Vol 19 ◽  
pp. 14-21 ◽  
Author(s):  
Meisam Shabanian ◽  
Mehdi Khoobi ◽  
Farideh Hemati ◽  
Hossein Ali Khonakdar ◽  
Khalil Faghihi ◽  
...  

2016 ◽  
Vol 2 ◽  
pp. 15-18 ◽  
Author(s):  
Marina I. Voronova ◽  
Oleg V. Surov ◽  
Sabir S. Guseinov ◽  
Anatoly G. Zakharov

Forests ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 777
Author(s):  
Shuang-Shuang Wu ◽  
Xin Tao ◽  
Wei Xu

Intending to achieve more green and economical graphene impregnated modified fast-growing poplar wood veneer for heat conduction, this study proposes and investigates the feasibility of modified veneer with graphene/Polyvinyl alcohol (Gr/PVA) impregnation mixture to improve its thermal conductivity. The absorbance and viscosity of the Gr/PVA impregnation mixtures are observed to expound the Gr/PVA ratio effects on the mixtures. Simultaneously, the weight percent gain, chromatic aberration, and thermal conductivity of the modified veneers are measured to determine the impregnation effect and the optimal impregnation formula. Further, the chemical structure, crystallinity, and thermal stability of the optimal sample impregnated with Gr/PVA are tested. The results show that the thermal properties of the Gr/PVA impregnated modified veneer have not all been improved. Still, both the dispersibility of the impregnation mixtures and the impregnation effect is affected by the Gr/PVA ratio. The data shows that the optimal thermal conductivity of modified veneer, which is up to 0.22 W·m−1·K−1 and 2.4 times the untreated one, is dipped by the mixture of 10 wt.% PVA concentration and 2 wt.% MGEIN addition. According to the characterization tests, the crystallinity of the modified veneer reduces, but the thermal stability improves.


Cellulose ◽  
2018 ◽  
Vol 26 (3) ◽  
pp. 1747-1755 ◽  
Author(s):  
Ting Zhou ◽  
Xudong Cheng ◽  
Yuelei Pan ◽  
Congcong Li ◽  
Lunlun Gong

2021 ◽  
Author(s):  
Anderson F. Manoel ◽  
Pedro Claro ◽  
Luiz H. C. Mattoso ◽  
Jose M. Marconcini ◽  
Gerson L. Mantovani

Abstract The aim of this work was to develop polymer blends of plasticized thermoplastic waxy starch (TPS) and poly(ɛ-caprolactone) (PCL) using the largest amount of TPS possible to obtain a biodegradable material motivated by sustainability issues and to replace petrochemical-based polymers with alternatives based on biopolymers. Addition of TPS to other polymers has been used to obtain cheaper and increasingly biodegradable final products. However, TPS presents limited mechanical properties, and mixing with other polymers such as PCL is necessary to overcome these limitations and improve its processability. TPS was processed by extrusion and thermo-compression using 30 wt% glycerol. The blends were suitably processed by extrusion and further injected. The TPS/PCL blends were studied by varying the amount of PCL in a range of 10 wt% in increasing order of addition. Thermal analysis showed that introducing PCL in TPS increased Tonset because of the higher thermal stability of the former, and that the obtained blends presented a behavior intermediate to that of neat polymers.


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