scholarly journals Green Hydrogen Separation from Nitrogen by Mixed‐Matrix Membranes Consisting of Nanosized Sodalite Crystals

ChemSusChem ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 4529-4537 ◽  
Author(s):  
Ge Yang ◽  
Hailing Guo ◽  
Zixi Kang ◽  
Lei Zhao ◽  
Shou Feng ◽  
...  
2019 ◽  
Vol 55 (49) ◽  
pp. 7101-7104 ◽  
Author(s):  
Chi Zhang ◽  
Baisong Liu ◽  
Gaimei Wang ◽  
Guangli Yu ◽  
Xiaoqin Zou ◽  
...  

Very selective and permeable membranes for hydrogen separation have been fabricated by hybridizing CAU-21 MOF with a small aperture and PIM-1 polymer with high porosity.


Author(s):  
Abhishek Kumar ◽  
Liang Huang ◽  
Leiqing Hu ◽  
Deqiang Yin ◽  
Haiqing Lin ◽  
...  

Palladium and palladium alloy nanowires (PdM; M= Ag, Ni, Cu, Y) of varying compositions were synthesized by facile and scalable one-pot polyol reduction of metallic salts using poly(vinylpyrrolidone) (PVP) as...


2019 ◽  
Vol 582 ◽  
pp. 381-390 ◽  
Author(s):  
Ju Sung Kim ◽  
Sun Ju Moon ◽  
Ho Hyun Wang ◽  
Seungju Kim ◽  
Young Moo Lee

2020 ◽  
Vol 8 (29) ◽  
pp. 14713-14720 ◽  
Author(s):  
Rujing Hou ◽  
Bader S. Ghanem ◽  
Stefan J. D. Smith ◽  
Cara M. Doherty ◽  
Caitlin Setter ◽  
...  

Porous PAF-1 addition accelerated TPIM-2 polymer chain densification and resulted in both improved hydrogen permeability and selectivity.


2010 ◽  
Vol 350 (1-2) ◽  
pp. 340-346 ◽  
Author(s):  
Asim Laeeq Khan ◽  
Angels Cano-Odena ◽  
Biotza Gutiérrez ◽  
Cristina Minguillón ◽  
Ivo F.J. Vankelecom

Membranes ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 666
Author(s):  
Chong Yang Chuah ◽  
Xu Jiang ◽  
Kunli Goh ◽  
Rong Wang

Membrane separation is a compelling technology for hydrogen separation. Among the different types of membranes used to date, the mixed-matrix membranes (MMMs) are one of the most widely used approaches for enhancing separation performances and surpassing the Robeson upper bound limits for polymeric membranes. In this review, we focus on the recent progress in MMMs for hydrogen separation. The discussion first starts with a background introduction of the current hydrogen generation technologies, followed by a comparison between the membrane technology and other hydrogen purification technologies. Thereafter, state-of-the-art MMMs, comprising emerging filler materials that include zeolites, metal-organic frameworks, covalent organic frameworks, and graphene-based materials, are highlighted. The binary filler strategy, which uses two filler materials to create synergistic enhancements in MMMs, is also described. A critical evaluation on the performances of the MMMs is then considered in context, before we conclude with our perspectives on how MMMs for hydrogen separation can advance moving forward.


2020 ◽  
Author(s):  
Muayad Al-shaeli ◽  
Stefan J. D. Smith ◽  
Shanxue Jiang ◽  
Huanting Wang ◽  
Kaisong Zhang ◽  
...  

<p>In this study, novel <a>mixed matrix polyethersulfone (PES) membranes</a> were synthesized by using two different kinds of metal organic frameworks (MOFs), namely UiO-66 and UiO-66-NH<sub>2</sub>. The composite membranes were characterised by SEM, EDX, FTIR, PXRD, water contact angle, porosity, pore size, etc. Membrane performance was investigated by water permeation flux, flux recovery ratio, fouling resistance and anti-fouling performance. The stability test was also conducted for the prepared mixed matrix membranes. A higher reduction in the water contact angle was observed after adding both MOFs to the PES and sulfonated PES membranes compared to pristine PES membranes. An enhancement in membrane performance was observed by embedding the MOF into PES membrane matrix, which may be attributed to the super-hydrophilic porous structure of UiO-66-NH<sub>2</sub> nanoparticles and hydrophilic structure of UiO-66 nanoparticles that could accelerate the exchange rate between solvent and non-solvent during the phase inversion process. By adding the MOFs into PES matrix, the flux recovery ratio was increased greatly (more than 99% for most mixed matrix membranes). The mixed matrix membranes showed higher resistance to protein adsorption compared to pristine PES membranes. After immersing the membranes in water for 3 months, 6 months and 12 months, both MOFs were stable and retained their structure. This study indicates that UiO-66 and UiO-66-NH<sub>2</sub> are great candidates for designing long-term stable mixed matrix membranes with higher anti-fouling performance.</p>


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