Ionic‐Liquid‐Modified Click‐Based Porous Organic Polymers for Controlling Capture and Catalytic Conversion of CO 2

ChemSusChem ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 180-187 ◽  
Author(s):  
Caiyan Cui ◽  
Rongjian Sa ◽  
Zixiao Hong ◽  
Hong Zhong ◽  
Ruihu Wang





2017 ◽  
Vol 8 (11) ◽  
pp. 1833-1839 ◽  
Author(s):  
Shuang Hao ◽  
Yuchuan Liu ◽  
Chuning Shang ◽  
Zhiqiang Liang ◽  
Jihong Yu

A class of imidazole ionic liquid functionalized porous organic polymers has been synthesized by the Friedel–Crafts alkylation reaction. The resulting materials show high CO2 uptake and catalytic activity in the syntheses of benzimidazole derivatives.



2019 ◽  
Author(s):  
ARKAPRABHA GIRI ◽  
MD. Waseem Hussain ◽  
BAHADUR SK ◽  
Abhijit Patra

Taking <i>C</i>-phenylresorcin[4]arene (RN4) as a model building block, we fabricated a series of porous organic polymers (POPs: RN4-OH, RN4-Az-OH, and RN4-F) where the surface area was enhanced up to ~8 folds (1229 m<sup>2 </sup>g<sup>-1</sup>) than that of the pristine cavitand (156 m<sup>2 </sup>g<sup>-1</sup>). The advantage of connecting the 0D porous cavitands was demonstrated through three environmentally relevant applications, namely, catalytic conversion of CO<sub>2</sub> to value-added products, selective gas (CO<sub>2</sub>, H<sub>2</sub>) uptake, and the charge-specific size-selective separation of organic micropollutants from water. In all the cases, RN4-derived POPs have outperformed the pristine 0D porous macrocyclic cavitand.



2019 ◽  
Author(s):  
ARKAPRABHA GIRI ◽  
MD. Waseem Hussain ◽  
BAHADUR SK ◽  
Abhijit Patra

Taking <i>C</i>-phenylresorcin[4]arene (RN4) as a model building block, we fabricated a series of porous organic polymers (POPs: RN4-OH, RN4-Az-OH, and RN4-F) where the surface area was enhanced up to ~8 folds (1229 m<sup>2 </sup>g<sup>-1</sup>) than that of the pristine cavitand (156 m<sup>2 </sup>g<sup>-1</sup>). The advantage of connecting the 0D porous cavitands was demonstrated through three environmentally relevant applications, namely, catalytic conversion of CO<sub>2</sub> to value-added products, selective gas (CO<sub>2</sub>, H<sub>2</sub>) uptake, and the charge-specific size-selective separation of organic micropollutants from water. In all the cases, RN4-derived POPs have outperformed the pristine 0D porous macrocyclic cavitand.



2021 ◽  
Author(s):  
Zhifeng Dai ◽  
Yuanfei Bao ◽  
Jindong Yuan ◽  
Jinzhong Yao ◽  
Yubing Xiong

Through a facile post synthetic method, different kinds of polar group functionalized ionic liquid porous organic polymers (POP-PA-COOH, POP-PA-OH, POP-PA-NH2) were obtained. The materials can be used as efficient heterogeneous...



ChemSusChem ◽  
2017 ◽  
Vol 10 (24) ◽  
pp. 4855-4863 ◽  
Author(s):  
Hong Zhong ◽  
Yanqing Su ◽  
Xingwei Chen ◽  
Xiaoju Li ◽  
Ruihu Wang


2018 ◽  
Vol 6 (32) ◽  
pp. 15564-15568 ◽  
Author(s):  
Jiangtao Jia ◽  
Zhijie Chen ◽  
Youssef Belmabkhout ◽  
Karim Adil ◽  
Prashant M. Bhatt ◽  
...  

A series of porous organic polymers (POPs) were synthesized based on the tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. This synthetic exploration afforded a drastic porosity alteration/enhancement of the unveiled POPs.





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