Aluminium Functionalized Germanes: Intramolecular Activation of Ge-H Bonds, Formation of a Dihydrogen Bond and Facile Hydrogermylation of Unsaturated Substrates

2019 ◽  
Vol 2019 (28) ◽  
pp. 3287-3300 ◽  
Author(s):  
Christian Honacker ◽  
Benedikt Kappelt ◽  
Mirosław Jabłoński ◽  
Alexander Hepp ◽  
Marcus Layh ◽  
...  
Keyword(s):  
Dihydrogen Bond ◽  
Intramolecular Activation

Intramolecular Activation of Pepsinogen

1977 ◽  
pp. 85-102 ◽  
Author(s):  
Jean A. Hartsuck ◽  
Joseph Marciniszyn ◽  
Jung San Huang ◽  
Jordan Tang
Keyword(s):  
Intramolecular Activation

Proton Affinity Correlations between Hydrogen and Dihydrogen Bond Acceptors

2007 ◽  
Vol 111 (16) ◽  
pp. 3178-3183 ◽  
Author(s):  
Prashant Chandra Singh ◽  
G. Naresh Patwari
Keyword(s):  
Proton Affinity ◽  
Dihydrogen Bond

Monocyclopentadienylhydride Derivatives of Ruthenium:  Stereoselective Proton Transfer and Proton-Hydride Exchange in an Extremely Short Dihydrogen Bond

2004 ◽  
Vol 126 (22) ◽  
pp. 7049-7062 ◽  
Author(s):  
Ester Cayuela ◽  
Félix A. Jalón ◽  
Blanca R. Manzano ◽  
Gustavo Espino ◽  
Walter Weissensteiner ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Dihydrogen Bond ◽  
Derivatives Of

Cyclometallation Reactions in the Fe(dprpe)2 System [dprpe = 1,2-Bis(dipropylphosphino)ethane].

1999 ◽  
Vol 52 (11) ◽  
pp. 1005 ◽  
Author(s):  
Murray V. Baker ◽  
Leslie D. Field
Keyword(s):  
Methyl Group ◽  
Thermal Elimination ◽  
Intramolecular Activation

Thermal elimination of methane from cis-FeH(CH3)(dprpe)2 [dprpe = 1,2-bis(dipropylphosphino)ethane] or photochemical elimination of dihydrogen from FeH2(dprpe)2 leads to the formation of three cyclometallation products. The products are believed to arise via a pathway in which the coordinatively unsaturated intermediate Fe(dprpe)2 undergoes intramolecular activation of a C–H bond of a dprpe methyl group. 1H and 31P n.m.r. spectroscopy were used to characterize the products and explore the reactions leading to their formation.

Sign in / Sign up

Export Citation Format

Share Document