Palladium-Catalyzed Diorganozinc Conjugate Additions to Enones: Preparative and Computational Studies

2013 ◽  
Vol 2013 (13) ◽  
pp. 2621-2626 ◽  
Author(s):  
Paula Lorenzo ◽  
José M. Aurrecoechea ◽  
Angel R. de Lera ◽  
Rosana Álvarez
Keyword(s):  
Computational Studies ◽  
Conjugate Additions ◽  
Palladium Catalyzed

Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis

Synthesis ◽  
2021 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Yang Wu ◽  
Feng Jin ◽  
Bao Xiaoguang ◽  
Ji-Bao Xia
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalysis ◽  
Computational Studies ◽  
Organic Azides ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Directing Group ◽  
And Control

An atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.

scholarly journals Palladium-Catalyzed C8-Selective C–H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric, and Solvation Effects on the Site Selectivity by Mechanistic and DFT Computational Studies

ACS Catalysis ◽  
2014 ◽  
Vol 5 (1) ◽  
pp. 167-175 ◽  
Author(s):  
David E. Stephens ◽  
Johant Lakey-Beitia ◽  
Abdurrahman C. Atesin ◽  
Tülay A. Ateşin ◽  
Gabriel Chavez ◽  
...  
Keyword(s):  
Computational Studies ◽  
Solvation Effects ◽  
Site Selectivity ◽  
Palladium Catalyzed

Enantioselective palladium catalyzed conjugate additions of ortho-substituted arylboronic acids to β,β-disubstituted cyclic enones: total synthesis of herbertenediol, enokipodin A and enokipodin B

2014 ◽  
Vol 12 (31) ◽  
pp. 5883-5890 ◽  
Author(s):  
Jeffrey Buter ◽  
Renée Moezelaar ◽  
Adriaan J. Minnaard
Keyword(s):  
Total Synthesis ◽  
Natural Product ◽  
Conjugate Addition ◽  
Natural Product Synthesis ◽  
Conjugate Additions ◽  
Arylboronic Acids ◽  
Cyclic Enones ◽  
Palladium Catalyzed

Palladium catalyzed asymmetric conjugate addition of ortho-substituted arylboronic acids to cyclic enones and its application in natural product synthesis.

ChemInform Abstract: Rhodium-and Palladium-Catalyzed Asymmetric Conjugate Additions

ChemInform ◽  
2011 ◽  
Vol 42 (50) ◽  
pp. no-no
Author(s):  
Guillaume Berthon ◽  
Tamio Hayashi
Keyword(s):  
Conjugate Additions ◽  
Palladium Catalyzed

Pd-catalyzed intramolecular sequential Heck cyclization and oxidation reactions: a facile pathway for the synthesis of substituted cycloheptenone evaluated using computational studies

2017 ◽  
Vol 41 (1) ◽  
pp. 278-284 ◽  
Author(s):  
Jayanta K. Ray ◽  
Sunanda Paul ◽  
Paramita Ray ◽  
Raju Singha ◽  
Davuluri Yogeswara Rao ◽  
...  
Keyword(s):  
Theoretical Approach ◽  
Computational Studies ◽  
Oxidation Reactions ◽  
Heck Cyclization ◽  
Palladium Catalyzed

A synthetic and theoretical approach towards the synthesis of cycloheptenone via palladium-catalyzed 7-exo-trig cyclization followed by the oxidation of cyclized alcohol.

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