Enhanced light harvesting in dye‐sensitized solar cells enabled by TiO 2 :Er 3+ , Yb 3+ upconversion phosphor particles as solar spectral converter and light scattering medium

Author(s):  
Xiuting Luo ◽  
Jeong Geun Cha ◽  
Guiming Fu ◽  
Hyung Woo Lee ◽  
Soo Hyung Kim
Coatings ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 13 ◽  
Author(s):  
Wen-Yao Huang ◽  
Tung-Li Hsieh

In this study, we prepared and analyzed the properties of hill-like hierarchically structured titanium dioxide (TiO2) photoanodes for dye-sensitized solar cells (DSSCs). We expected that the presence of appropriately aggregated TiO2 clusters in the photoanode layer would translate to relatively strong light scattering and dye loading, increasing the photovoltaic efficiency. A detailed light-harvesting study was performed by employing polyvinyl alcohol (PVA) polymers of different molecular weights as binders for the aggregation of the TiO2 nanoparticles (P-25 Degussa). Hence, we obtained a series of TiO2 films, presenting a variety of morphologies. Their reflection, as well as absorbance of light by the attached dye, the amount of dye loading, and the performance of the fabricated DSSC devices were investigated. Our optimized device, with a relatively high dye loading and good light harvesting ability, was able to enhance the short-circuit current (Jsc) in the DSSCs by 23%.


2020 ◽  
Vol 44 (25) ◽  
pp. 10545-10553
Author(s):  
Jia Yu ◽  
Yulin Yang ◽  
Chuanxiang Zhang ◽  
Ruiqing Fan ◽  
Ting Su

The TiO2/YbF3-Ho@TiO2 heterostructure with light-scattering and NIR-light harvesting characteristics can facilitate charge separation, suppress recombination process and prolong the lifetime of electrons.


RSC Advances ◽  
2017 ◽  
Vol 7 (61) ◽  
pp. 38506-38511 ◽  
Author(s):  
Haiyong Guo ◽  
Zhen Hu ◽  
Li Zhao ◽  
Li Wan ◽  
Yadan Wu ◽  
...  

A new strategy to improve the efficiency of dye-sensitized solar cells by using the external near-infrared light harvesting and light-scattering dual-functional upconversion (UC) material NaLuF4:Yb3+/Er3+ is proposed.


2011 ◽  
Vol 196 (4) ◽  
pp. 2416-2421 ◽  
Author(s):  
Kun-Mu Lee ◽  
Ying-Chan Hsu ◽  
Masashi Ikegami ◽  
Tsutomu Miyasaka ◽  
K.R. Justin Thomas ◽  
...  

2015 ◽  
Vol 3 (40) ◽  
pp. 20366-20374 ◽  
Author(s):  
Nianqing Fu ◽  
Yan Liu ◽  
Yanchun Liu ◽  
Wei Lu ◽  
Limin Zhou ◽  
...  

Hierarchical TiO2architecture with a remarkably improved surface area and light scattering effect was preparedviaone-step post-treatment for dye-sensitized solar cells, achieving a high efficiency of 8.82%.


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