Synthesis and Characterization of Carbonyl Group-6-Metal Derivatives with Ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N-naphthalen-1-yl-P,P-diphenylphosphinous Amide). Molecular Structure of cis-Tetracarbonyl[N-(diphenylpho

2013 ◽  
Vol 96 (4) ◽  
pp. 738-746 ◽  
Author(s):  
Harbi Tomah Al-Masri ◽  
Beshir M. Mohamed ◽  
Ziad Moussa ◽  
Mohamed H. Alkordi
Keyword(s):  
Molecular Structure ◽  
Carbonyl Group ◽  
Synthesis And Characterization ◽  
Group 6 ◽  
Metal Derivatives

Synthesis and characterization of group 6-9 metal-rich homo- and hetero-metallaboranes

2021 ◽  
Vol 98 (3) ◽  
pp. 100040
Author(s):  
Ranjit Bag ◽  
Suman Gomosta ◽  
Alaka Nanda Pradhan ◽  
Thierry Roisnel ◽  
Sundargopal Ghosh
Keyword(s):  
Synthesis And Characterization ◽  
Group 6

scholarly journals Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 97 ◽  
Author(s):  
Marie Gaschard ◽  
Farzaneh Nehzat ◽  
Thomas Cheminel ◽  
Bruno Therrien
Keyword(s):  
Molecular Structure ◽  
Single Crystal ◽  
General Formula ◽  
Structure Analysis ◽  
White Light ◽  
Light Irradiation ◽  
Synthesis And Characterization ◽  
X Ray

The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies.

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