Catalysis and photocatalysis by metal organic frameworks

2018 ◽  
Vol 47 (22) ◽  
pp. 8134-8172 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Zhaohui Li ◽  
Hermenegildo Garcia
Keyword(s):  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Solid Catalysts ◽  
Metal Organic

This review aims to provide different strategies employed to use MOFs as solid catalysts and photocatalysts in organic transformations.

scholarly journals A Review on Metal-Organic Frameworks as Congenial Heterogeneous Catalysts for Potential Organic Transformations

2021 ◽  
Vol 9 ◽  
Author(s):  
Kranthi Kumar Gangu ◽  
Sreekantha B. Jonnalagadda
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Value Added ◽  
Biological Molecules ◽  
Full Potential ◽  
Organic Transformations ◽  
Solid Catalysts ◽  
Metal Organic ◽  
Catalytic Active Sites

Metal-organic frameworks (MOFs) have emerged as versatile candidates of interest in heterogeneous catalysis. Recent research and developments with MOFs positively endorse their role as catalysts in generating invaluable organic compounds. To harness the full potential of MOFs in value-added organic transformation, a comprehensive look at how these materials are likely to involve in the catalytic processes is essential. Mainstays of MOFs such as metal nodes, linkers, encapsulation materials, and enveloped structures tend to produce capable catalytic active sites that offer solutions to reduce human efforts in developing new organic reactions. The main advantages of choosing MOFs as reusable catalysts are the flexible and robust skeleton, regular porosity, high pore volume, and accessible synthesis accompanied with cost-effectiveness. As hosts for active metals, sole MOFs, modified MOFs, and MOFs have made remarkable advances as solid catalysts. The extensive exploration of the MOFs possibly led to their fast adoption in fabricating new biological molecules such as pyridines, quinolines, quinazolinones, imines, and their derivatives. This review covers the varied MOFs and their catalytic properties in facilitating the selective formation of the product organic moieties and interprets MOF’s property responsible for their elegant performance.

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Metal–organic frameworks as catalytic selectivity regulators for organic transformations

2021 ◽  
Author(s):  
Jun Guo ◽  
Yutian Qin ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Chang Long ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Research Topic ◽  
Organic Transformations ◽  
Catalytic Selectivity ◽  
Challenging Research ◽  
Metal Organic

Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based heterogeneous catalysts have been an intriguing but challenging research topic in both the chemistry and materials communities.

Metal-Organic Frameworks as Single-Site Solid Catalysts for Asymmetric Reactions

2012 ◽  
Vol 52 (7) ◽  
pp. 591-603 ◽  
Author(s):  
Joseph M. Falkowski ◽  
Sophie Liu ◽  
Wenbin Lin
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Asymmetric Reactions ◽  
Solid Catalysts ◽  
Metal Organic

scholarly journals Recent Advances in Metal-Organic Frameworks for Heterogeneous Catalyzed Organic Transformations

2016 ◽  
Vol 01 (01) ◽  
Author(s):  
Sandip Sabale ◽  
Jian Zheng ◽  
Rama S Vemuri ◽  
Xiao-Ying Yu ◽  
Peter McGrail B ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Recent Advances ◽  
Metal Organic

A mechanistic approach towards the photocatalytic organic transformations over functionalised metal organic frameworks: a review

2018 ◽  
Vol 8 (3) ◽  
pp. 679-696 ◽  
Author(s):  
Satyabrata Subudhi ◽  
Dharitri Rath ◽  
K. M. Parida
Keyword(s):  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Mechanistic Approach ◽  
Metal Organic

This review focuses on the possible mechanisms involved in the organic transformations occurring through photocatalysis over functionalised metal–organic frameworks.

Surveying Iron–Organic Framework TAL-1-Derived Materials in Ligandless Heterogeneous Oxidative Catalytic Transformations of Alkylarenes

Synlett ◽  
2019 ◽  
Vol 30 (13) ◽  
pp. 1536-1540
Author(s):  
Kefeng Ping ◽  
Mahboob Alam ◽  
Maike Käärik ◽  
Jaan Leis ◽  
Nadežda Kongi ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Polycrystalline Iron ◽  
Catalytic Transformations ◽  
Metal Organic ◽  
Organic Framework

The use of carbonized materials derived from metal–organic frameworks (MOFs) in catalytic organic transformations is less well explored than is the use of MOFs. Here, we survey the oxidative performance of heterogeneous catalyst materials derived from the polycrystalline iron–organic framework TAL-1.

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