Synthesis and Characterization of Novel Monoazo Naphthalimide Disperse Dyes Containing Carboxylic Acid Group with High Heat Fastness Properties

2008 ◽  
Vol 55 (6) ◽  
pp. 1300-1307 ◽  
Author(s):  
Moosa Sadeghi Kiakhani ◽  
Kamaladin Gharanjig ◽  
Mokhtar Arami ◽  
Javad Mokhtari ◽  
Niyaz Mohammad Mahmoodi
Keyword(s):  
Carboxylic Acid ◽  
Acid Group ◽  
High Heat ◽  
Synthesis And Characterization ◽  
Disperse Dyes ◽  
Fastness Properties ◽  
Carboxylic Acid Group

scholarly journals Crystallographic and spectroscopic characterization of (R)-O-acetylmandelic acid

2016 ◽  
Vol 72 (7) ◽  
pp. 901-903
Author(s):  
Cady Cirbes ◽  
Joseph M. Tanski
Keyword(s):  
Hydrogen Bonding ◽  
Carboxylic Acid ◽  
Mandelic Acid ◽  
Phenylacetic Acid ◽  
Spectroscopic Characterization ◽  
Acid Group ◽  
Intermolecular Hydrogen Bonding ◽  
Carboxylic Acid Group ◽  
Donor Acceptor

The title compound [systematic name: (R)-(−)-2-acetoxy-2-phenylacetic acid], C10H10O4, is a resolved chiral ester derivative of mandelic acid. The compound contains an acetate group and a carboxylic acid group, which engage in intermolecular hydrogen bonding, forming chains extending parallel to [001] with a short donor–acceptor hydrogen-bonding distance of 2.676 (2) Å.

scholarly journals Characterization of autohydrolysis aspen (P. tremuloides) lignins. Part 3. Infrared and ultraviolet studies of extracted autohydrolysis lignin

1979 ◽  
Vol 57 (19) ◽  
pp. 2603-2611 ◽  
Author(s):  
Miranda G. S. Chua ◽  
Morris Wayman
Keyword(s):  
Carboxylic Acid ◽  
Blocking Agent ◽  
Acid Group ◽  
Hydroxybenzoic Acid ◽  
Aspen Wood ◽  
Carboxylic Acid Group ◽  
Carboxylic Acid Groups ◽  
Acidic Conditions ◽  
Lignin Macromolecule

Infrared and ultraviolet studies of the lignins extracted from extractive-free aspen wood meal after autohydrolysis at 195 °C for periods varying from 5 min to 2 h indicated that these lignins were functionally modified and different from aspen milled wood lignin. The extracted lignins changed from a guaiacyl–syringyl type lignin to a syringyl-deficient type lignin with increasing autohydrolysis time. Extracted lignins were also observed to contain unconjugated β-ketone groups and conjugated carboxylic acid groups. It is proposed that the unconjugated β-ketone groups resulted from the depolymerization reactions of the lignin macromolecule under acidic conditions which formed monomeric, dimeric, and oligomeric/polymeric lignin fragments with Hibbert's ketone side chains. The conjugated carboxylic acid group observed to be present was attributed to p-hydroxybenzoic acid. p-Hydroxybenzoic acid has been postulated as contributing to the extractability of aspen lignin by acting as a blocking agent in the repolymerization of lignin fragments to form insoluble lignin.

scholarly journals The first structural characterization of the protonated azacyclam ligand in catena-poly[[[(perchlorato)copper(II)]-μ-3-(3-carboxypropyl)-1,5,8,12-tetraaza-3-azoniacyclotetradecane] bis(perchlorate)]

2019 ◽  
Vol 75 (11) ◽  
pp. 1700-1704
Author(s):  
Liudmyla V. Tsymbal ◽  
Vladimir B. Arion ◽  
Yaroslaw D. Lampeka
Keyword(s):  
Carboxylic Acid ◽  
Metal Ion ◽  
Macrocyclic Ligand ◽  
Acid Group ◽  
Distorted Octahedral Geometry ◽  
Equatorial Orientation ◽  
Carboxylic Acid Group ◽  
Bond Lengths ◽  
Distorted Octahedral

The asymmetric unit of the title compound, catena-poly[[[(perchlorato-κO)copper(II)]-μ-3-(3-carboxypropyl)-1,5,8,12-tetraaza-3-azoniacyclotetradecane-κ4 N 1,N 5,N 8,N 12] bis(perchlorate)], {[Cu(C13H30N5O2)(ClO4)](ClO4)2} n , (I), consists of a macrocyclic cation, one coordinated perchlorate anion and two perchlorate ions as counter-anions. The metal ion is coordinated in a tetragonally distorted octahedral geometry by the four secondary N atoms of the macrocyclic ligand, the mutually trans O atoms of the perchlorate anion and the carbonyl O atom of the protonated carboxylic acid group of a neighbouring cation. The average equatorial Cu—N bond lengths [2.01 (6) Å] are significantly shorter than the axial Cu—O bond lengths [2.379 (8) Å for carboxylate and average 2.62 (7) Å for disordered perchlorate]. The coordinated macrocyclic ligand in (I) adopts the most energetically favourable trans-III conformation with an equatorial orientation of the substituent at the protonated distal 3-position N atom in a six-membered chelate ring. The coordination of the carboxylic acid group of the cation to a neighbouring complex unit results in the formation of infinite chains running along the b-axis direction, which are crosslinked by N—H...O hydrogen bonds between the secondary amine groups of the macrocycle and O atoms of the perchlorate counter-anions to form sheets lying parallel to the (001) plane. Additionally, the extended structure of (I) is consolidated by numerous intra- and interchain C—H...O contacts.

scholarly journals Crystallographic and spectroscopic characterization of 4-nitro-2-(trifluoromethyl)benzoic acid and 4-nitro-3-(trifluoromethyl)benzoic acid

2019 ◽  
Vol 75 (4) ◽  
pp. 524-528
Author(s):  
George L. Diehl III ◽  
Lisa Je ◽  
Joseph M. Tanski
Keyword(s):  
Hydrogen Bonding ◽  
Carboxylic Acid ◽  
Benzoic Acid ◽  
Nitro Group ◽  
Spectroscopic Characterization ◽  
Acid Group ◽  
Carboxylic Acid Group ◽  
Donor Acceptor ◽  
Graph Set

The title compounds, both C8H4F3NO4, represent two isomers of nitro trifluoromethyl benzoic acid. The compounds each contain a nitro functionality para to the carboxylic acid group, with the trifluoromethyl substituent ortho to the acid group in the 2-isomer and ortho to the nitro group in the 3-isomer. The regiochemistry with respect to the trifluoromethyl group results in steric interactions that rotate the carboxylic acid group or the nitro group out of the aromatic plane in the 2- and 3-isomer, respectively. Each molecule engages in intermolecular hydrogen bonding, forming head-to-tail dimers with graph-set notation R 2 2(8) and donor–acceptor hydrogen-bonding distances of 2.7042 (14) Å in the 2-isomer and 2.6337 (16) in the 3-isomer. Recrystallization attempts did not yield untwinned crystals.

The inner salt 4-carboxy-2-(pyridinium-4-yl)-1H-imidazole-5-carboxylate monohydrate

2006 ◽  
Vol 62 (7) ◽  
pp. o2751-o2752 ◽  
Author(s):  
Ting Sun ◽  
Jian-Ping Ma ◽  
Ru-Qi Huang ◽  
Yu-Bin Dong
Keyword(s):  
Carboxylic Acid ◽  
Dihedral Angle ◽  
Title Compound ◽  
Acid Group ◽  
Planar Structure ◽  
Carboxyl Group ◽  
Carboxylic Acid Group ◽  
Pyridyl Group ◽  
Compound C

In the title compound, C10H7N3O4·H2O, one carboxyl group is deprotonated and the pyridyl group is protonated. The inner salt molecule has a planar structure, apart from the carboxylic acid group, which is tilted from the imidazole plane by a small dihedral angle of 7.3 (3)°.

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