Dry reforming of methane by La 0. 5 Sr 0 . 5 NiO 3 perovskite oxides: influence of preparation method on performance and structural features of the catalysts

2020 ◽  
Vol 95 (11) ◽  
pp. 2911-2920
Author(s):  
Maryam Mousavi ◽  
Ali Nakhaei Pour ◽  
Mostafa Gholizadeh ◽  
Ali Mohammadi ◽  
Seyed Mehdi Kamali Shahri
2019 ◽  
Vol 43 (27) ◽  
pp. 10763-10773 ◽  
Author(s):  
Maryam Mousavi ◽  
Ali Nakhaei Pour

LaNiO3 and LaNi0.5Co0.5O3 as perovskites were synthesized in magnetized and non-magnetized water and the activity of the catalysts was evaluated in the methane dry reforming reaction with CO2.


2017 ◽  
Vol 12 (3-4) ◽  
pp. 174-184 ◽  
Author(s):  
T. F. Sheshko ◽  
Yu. M. Serov ◽  
T. A. Kryuchkova ◽  
I. A. Khayrullina ◽  
I. V. Chislova ◽  
...  

Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 621 ◽  
Author(s):  
Constantinos M. Damaskinos ◽  
Michalis A. Vasiliades ◽  
Vassilis N. Stathopoulos ◽  
Angelos M. Efstathiou

The present work discusses the effect of CeO2 synthesis method (thermal decomposition (TD), precipitation (PT), hydrothermal (HT), and sol-gel (SG)) on the carbon pathways of dry reforming of methane with carbon dioxide (DRM) applied at 750 °C over 5 wt% Ni/CeO2. In particular, specific transient and isotopic experiments (use of 13CO, 13CO2, and 18O2) were designed and conducted in an attempt at providing insights about the effect of support’s preparation method on the concentration (mg gcat−1), reactivity towards oxygen, and transient evolution rates (μmol gcat−1 s−1) of the inactive carbon formed under (i) CH4/He (methane decomposition), (ii) CO/He (reverse Boudouard reaction), and (iii) the copresence of the two (CH4/CO/He, use of 13CO). Moreover, important information regarding the relative contribution of CH4 and CO2 activation routes towards carbon formation under DRM reaction conditions was derived by using isotopically labelled 13CO2 in the feed gas stream. Of interest was also the amount, and the transient rate, of carbon removal via the participation of support’s labile active oxygen species.


2008 ◽  
Vol 344 (1-2) ◽  
pp. 10-19 ◽  
Author(s):  
M.E. Rivas ◽  
J.L.G. Fierro ◽  
M.R. Goldwasser ◽  
E. Pietri ◽  
M.J. Pérez-Zurita ◽  
...  

Author(s):  
Gaukhar E. Ergazieva ◽  
Moldir M. Telbayeva ◽  
Anna N. Popova ◽  
Zinfer R. Ismagilov ◽  
Kusman Dossumov ◽  
...  

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