Separation of phenol-containing pyrolysis products using comprehensive two-dimensional chromatography with columns based on pyridinium ionic liquids

2016 ◽  
Vol 39 (19) ◽  
pp. 3754-3760 ◽  
Author(s):  
Mikhail V. Shashkov ◽  
Vladimir N. Sidelnikov
Keyword(s):  
Ionic Liquids ◽  
Two Dimensional ◽  
Pyrolysis Products

Two-dimensional ultrafast vibrational spectroscopy of azides in ionic liquids reveals solute-specific solvation

2015 ◽  
Vol 17 (40) ◽  
pp. 26575-26579 ◽  
Author(s):  
Samrat Dutta ◽  
Zhe Ren ◽  
Thomas Brinzer ◽  
Sean Garrett-Roe
Keyword(s):  
Ionic Liquids ◽  
Vibrational Spectroscopy ◽  
Two Dimensional ◽  
Specific Solvation ◽  
2D Ir ◽  
Ir Studies ◽  
Ultrafast Vibrational Spectroscopy

2D-IR studies of organic and inorganic azides dissolved in ionic liquids show different solvation structures and picosecond dynamics.

scholarly journals V2O2F4(H2O)2·H2O: a new V4+layer structure related to VOF3

2016 ◽  
Vol 72 (1) ◽  
pp. 80-83 ◽  
Author(s):  
Cameron Black ◽  
Philip Lightfoot
Keyword(s):  
Ionic Liquids ◽  
Title Compound ◽  
Solvothermal Synthesis ◽  
Layer Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Frustrated Magnets ◽  
Two Dimensional ◽  
Triangular Lattices ◽  
Solvothermal Conditions

VIVoxyfluorides are of interest as frustrated magnets. The successful synthesis of two-dimensionally connected vanadium(IV) oxyfluoride structures generally requires the use of ionic liquids as solvents. During solvothermal synthesis experiments aimed at producing two- and three-dimensional vanadium(IV) selenites with triangular lattices, the title compound, diaquatetra-μ-fluorido-dioxidodivanadium(IV) monohydrate, V2O2F4(H2O)2·H2O, was discovered and features a new infinite V4+-containing two-dimensional layer comprised of fluorine-bridged corner- and edge-sharing VOF4(H2O) octahedral building units. The synthesis was carried out under solvothermal conditions. The V4+centre exhibits a typical off-centring, with a short V=O bond and an elongatedtrans-V—F bond. Hydrogen-bonded water molecules occur between the layers. The structure is related to previously reported vanadium oxyfluoride structures, in particular, the same layer topology is seen in VOF3.

Two-dimensional molybdenum disulfide based membranes for ionic liquids separation

2019 ◽  
Vol 226 ◽  
pp. 109-116 ◽  
Author(s):  
Jiashi Yin ◽  
Phuoc Hoang-Hanh Duong ◽  
Shuai Tan ◽  
Katie Dongmei Li-Oakey
Keyword(s):  
Ionic Liquids ◽  
Molybdenum Disulfide ◽  
Two Dimensional

scholarly journals Research Progress on the Preparation and Properties of Two Dimensional Structure of Ionic Liquids

2021 ◽  
Vol 79 (4) ◽  
pp. 443
Author(s):  
Yumiao Lu ◽  
Wei Chen ◽  
Yanlei Wang ◽  
Feng Huo ◽  
Yihui Dong ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Research Progress ◽  
Dimensional Structure ◽  
Two Dimensional

scholarly journals Role of the Solvent–Surfactant Duality of Ionic Liquids in Directing Two-Dimensional Particle Assembly

2020 ◽  
Vol 124 (44) ◽  
pp. 24215-24222
Author(s):  
Lili Liu ◽  
Duo Song ◽  
Biao Jin ◽  
Michael A. Sinnwell ◽  
Jun Liu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Two Dimensional ◽  
Particle Assembly

scholarly journals Two-Dimensional FTIR as a Tool to Study the Chemical Interactions within Cellulose-Ionic Liquid Solutions

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Kalyani Kathirgamanathan ◽  
Warren J. Grigsby ◽  
Jafar Al-Hakkak ◽  
Neil R. Edmonds
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Network Structure ◽  
Solution Viscosity ◽  
Two Dimensional ◽  
Ambient Temperatures ◽  
Heating And Cooling ◽  
Solution Rheology ◽  
Higher Temperature

In this study two-dimensional FTIR analysis was applied to understand the temperature effects on processing cellulose solutions in imidazolium-based ionic liquids. Analysis of the imidazolium ionνC2–H peak revealed hydrogen bonding within cellulose solutions to be dynamic on heating and cooling. The extent of hydrogen bonding was stronger on heating, consistent with greater ion mobility at higher temperature when the ionic liquid network structure is broken. At ambient temperatures a blue shiftedνC2–H peak was indicative of greater cation-anion interactions, consistent with the ionic liquid network structure. Both cellulose and water further impact the extent of hydrogen bonding in these solutions. The FTIR spectral changes appeared gradual with temperature and contrast shear induced rheology changes which were observed on heating above 70°C and cooling below 40°C. The influence of cellulose on solution viscosity was not distinguished on initial heating as the ionic liquid network structure dominates rheology behaviour. On cooling, the quantity of cellulose has a greater influence on solution rheology. Outcomes suggest processing cellulose in ionic liquids above 40°C and to reduce the impacts of cation-anion effects and enhance solubilisation, processing should be done at 70°C.

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