Mechanism and linear free energy relationships in the kinetics of formation of bicyclo[3.3.1]nonane derivatives from 1,3,5-trinitrobenzene, phenyl-substituted 1-benzyl-1-(ethoxycarbonyl)-2-propanones, and triethylamine

2011 ◽  
Vol 43 (9) ◽  
pp. 467-473 ◽  
Author(s):  
D. Kalaivani ◽  
M. Vasuki ◽  
S. Santhi
Keyword(s):  
Free Energy ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Kinetics Of Formation ◽  
Energy Relationships ◽  
Kinetics Of ◽  
Substituted 1

Establishing linear-free-energy relationships for the quadricyclane-to-norbornadiene reaction

2020 ◽  
Vol 18 (11) ◽  
pp. 2113-2119 ◽  
Author(s):  
Mads Mansø ◽  
Anne Ugleholdt Petersen ◽  
Kasper Moth-Poulsen ◽  
Mogens Brøndsted Nielsen
Keyword(s):  
Free Energy ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships ◽  
Kinetics Of ◽  
Selection Of

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.

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