Effect of a triazine ring-containing charring agent on fire retardancy and thermal degradation of intumescent flame retardant epoxy resins

2010 ◽  
Vol 22 (12) ◽  
pp. 2480-2487 ◽  
Author(s):  
Xin Wang ◽  
Yuan Hu ◽  
Lei Song ◽  
Weiyi Xing ◽  
Hongdian Lu ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Flame Retardant ◽  
Epoxy Resins ◽  
Intumescent Flame Retardant ◽  
Triazine Ring ◽  
Fire Retardancy ◽  
Charring Agent

The Effect of Kaolin Clay on Fire Retardancy and Thermal Degradation of Intumescent Flame Retardant (IFR)/Natural Rubber Composite

2013 ◽  
Vol 844 ◽  
pp. 334-337 ◽  
Author(s):  
Thiranan Thuechart ◽  
Wirunya Keawwattana
Keyword(s):  
Thermal Degradation ◽  
Natural Rubber ◽  
Flame Retardant ◽  
Cone Calorimeter ◽  
Intumescent Flame Retardant ◽  
Kaolin Clay ◽  
Fire Retardancy ◽  
Blowing Agent ◽  
Rubber Composite ◽  
Synergistic Agent

Study the effect of kaolin clay as a synergistic agent on flame retardancy and thermal degradation in natural rubber based on intumescent flame retardant (IFR); consisting of ammonium polyphosphate (APP) as acid source, pentaerythritol (PER) as a carbonization agent and melamine (ME) as a blowing agent was undertaken. The intumescent was examined at different loading (60, 80 and 100 phr). Kaolin clay was incorporated into flame retardant at four different concentrations (0.5, 1.0, 1.5 and 2.0 wt% of flame retardant) to investigate the synergism between the flame retardant materials. The flammability and thermal degradation of composites were characterized by UL-94 rating (vertical burning) test, cone calorimeter (CONE) and thermogravimetric analysis (TGA). All composites could meet the UL94V-0 standard. A synergist effect was observed when kaolin clay is used in combination with the intumescent flame-retardant through the TGA and CONE results. Moreover Scanning Electron Microscope (SEM) was done for the char morphology.

Thermal Stabilities and the Thermal Degradation Kinetics Study of the Flame Retardant Epoxy Resins

2014 ◽  
Vol 1053 ◽  
pp. 263-267 ◽  
Author(s):  
Xiu Juan Tian
Keyword(s):  
Thermal Stability ◽  
Thermal Degradation ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Epoxy Resins ◽  
Degradation Kinetics ◽  
Thermal Degradation Kinetics ◽  
Thermal Stabilities ◽  
Degradation Kinetic ◽  
Modified Epoxy

Thermal stability and thermal degradation kinetics of epoxy resins with 2-(Diphenylphosphinyl)-1, 4-benzenediol were investegated by thermogravimetric analysis (TGA) at different heating rates of 5 K/min, 10 K/min, 20 K/min and 40 K/min. The thermal degradation kinetic mechanism and models of the modified epoxy resins were determined by Coast Redfern method.The results showed that epoxy resins modified with the flame retardant had more thermal stability than pure epoxy resin. The solid-state decomposition mechanism of epoxy resin and the modified epoxy resin corresponded to the controlled decelerating ځ˽̈́˰̵̳͂͆ͅ˼˰̴̱̾˰̸̵̈́˰̵̸̳̱̹̽̾̓̽˰̶̳̹̾̈́̿̾̓ͅ˰̶˸ځ˹˰̵̵͇͂˰̃˸́˽ځ˹2/3. The introduction of phosphorus-containing flame retardant reduced thermal degradation rate of epoxy resins in the primary stage, and promote the formation of carbon layer.

Thermal degradation of DNA, an all-in-one natural intumescent flame retardant

2015 ◽  
Vol 113 ◽  
pp. 110-118 ◽  
Author(s):  
Jenny Alongi ◽  
Alessandro Di Blasio ◽  
John Milnes ◽  
Giulio Malucelli ◽  
Serge Bourbigot ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Flame Retardant ◽  
Intumescent Flame Retardant
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