Synthesis of functionalized copolymers and their compatibilization effects on acrylonitrile butadiene styrene/poly(butylene terephthalate) blends

2020 ◽  
Vol 60 (12) ◽  
pp. 2967-2978
Author(s):  
Kunquan Li ◽  
Wenjian Wu ◽  
Shengyong Chai ◽  
Lei Tang ◽  
Jide Li ◽  
...  
2014 ◽  
Vol 893 ◽  
pp. 228-234 ◽  
Author(s):  
Jun Chen ◽  
Ting Chen ◽  
Xin Ping Liu ◽  
Li Ren Xiao ◽  
Qing Rong Qian ◽  
...  

Glycidyl methacrylate (GMA) grafted acrylonitrile-butadiene-styrene (ABS) in the presence of styrene (St) monomer (AGS) was used as a compatibilizer in the immiscible poly(butylene terephthalate)/poly(acrylonitrile-styrene-acrylate) (PBT/ASA) blends. SEM analyses display a better dispersion of ASA particles in the PBT matrix with the content of AGS less than 4.0 wt% compared with the PBT/ASA blends. Rheological measurements show that the melt elasticity and melt strength of blends increase with increasing ABS-g-(GMA-co-St) content. The behavior of blends shifts from “liquid-like” to “solid-like” and the relaxation time moves to higher values by introducing AGS. 3.0 wt% AGS is the optimum concentration for PBT/ASA system.


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