Thermal and mechanical properties of diglycidylether of bisphenol A/ trimethylolpropane triglycidylether epoxy blends cured with benzylpyrazinium salts

2002 ◽  
Vol 51 (5) ◽  
pp. 386-392 ◽  
Author(s):  
Soo-Jin Park ◽  
Taek-Jin Kim ◽  
Hak-Yong Kim
2011 ◽  
Vol 239-242 ◽  
pp. 3253-3256 ◽  
Author(s):  
Li Huo ◽  
Jun Gang Gao ◽  
Yong Gang Du

The curing, thermal and mechanical properties of bi-component system for bisphenol A epoxy resin (BPAER) modified by liquid crystalline Sulfonyl bis(4,1-phenylene)bis[4-(2,3-epoxypro pyloxy)benzoate] (p-SBPEPB), with 4,4'-diaminodiphenyl ether (DDE) as a curing agent, were investigated. The effect of the different liquid crystalline contents and the heating rate on curing reaction was discussed. The results show that the curing peak temperature decreases, curing rate increases, the glass transition temperature (Tg)and impact strength all increase with adding of liquid crystalline p-SBPEPB when the content is not over 8wt%.


2019 ◽  
Vol 137 (8) ◽  
pp. 48404 ◽  
Author(s):  
Zahra Baig ◽  
Nadia Akram ◽  
Khalid Mahmood Zia ◽  
Muhammad Saeed ◽  
Muhammad Kaleem Khosa ◽  
...  

2018 ◽  
Vol 42 (13) ◽  
pp. 11202-11212 ◽  
Author(s):  
C. P. Sakthidharan ◽  
Pudupadi R. Sundararajan ◽  
Muthusamy Sarojadevi

Dicyanate esters (CEs) with a quinoline moiety were synthesized by treating bisphenols with cyanogen bromide in the presence of triethylamine and the structures were confirmed by FT-IR, and NMR spectral studies.


2003 ◽  
Vol 81 (3) ◽  
pp. 423-430 ◽  
Author(s):  
A. Fainleib ◽  
J. Grenet ◽  
M.R. Garda ◽  
J.M Saiter ◽  
O. Grigoryeva ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19666-19674 ◽  
Author(s):  
C. P. Sakthidharan ◽  
P. R. Sundararajan ◽  
M. Sarojadevi

A series of azomethine fictionalized cyanate ester and its epoxy blends were prepared and characterized.


2018 ◽  
Vol 22 ◽  
pp. 1-9 ◽  
Author(s):  
Syed Sajid Ali Shah ◽  
Habib Nasir ◽  
Noaman Ul-Haq

Polymer matrix plays a crucial role in the development of advanced light weight composite materials, and is mainly responsible for thermal and mechanical properties. These polymer matrices are usually thermosetting plastics due to their ease of processing. Thermoset resins were prepared using different compositions of dicyanate ester of bisphenol A and polyether imide and carbon fiber laminates were prepared by wet layup technique. Small amount of epoxy (diglycidyl ether of bisphenol A) was also added to the composites to improve the (interfacial) bonding between the carbon fiber and the resin. The Copper (II) oxalate with 1,5-pentanediol was used as a catalyst for the first time to reduce the curing time from eight hours to four hours. The catalyst has also reduced the curing temperature from 400°C to 250°C. The catalyst Copper (II) oxalate is commercially available. The plasticizer has improved the thermal and mechanical properties of the matrix significantly. The addition of epoxy to the thermoset resin improved the (interfacial) bonding between the resin and carbon fiber. FTIR results suggest that the polymerization reaction of dicyanate results in the formation of trizine ring with phenolic group. SEM results show the interaction of bisphenol A dicyanate (BPADCy) monomer to form polymer matrix. SEM images also represent a uniform anchoring of matrix on the individual carbon filament. It is clear from thermal analysis that sample having 85% BPADCy and 15% polyetherimide (BPR-2) shows the greater thermal stability which is due to the reaction of epoxy with cyanate matrix.


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