Induced intramolecularity in the reference reaction can be responsible for the low effective molarity of intramolecular general acid-base catalysis

Robert Pascal

doi:10.1002/poc.512

Induced intramolecularity in the reference reaction can be responsible for the low effective molarity of intramolecular general acid-base catalysis

Journal of Physical Organic Chemistry ◽

10.1002/poc.512 ◽

2002 ◽

Vol 15 (8) ◽

pp. 566-569 ◽

Cited By ~ 9

Author(s):

Robert Pascal

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid ◽

Effective Molarity ◽

Reference Reaction

Faculty Opinions recommendation of General acid-base catalysis mediated by nucleobases in the hairpin ribozyme.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.717959557.793462815 ◽

2012 ◽

Author(s):

Robert Batey

Keyword(s):

Base Catalysis ◽

Hairpin Ribozyme ◽

Acid Base ◽

General Acid

General acid base catalysis

Katalyse in Lösungen ◽

10.1007/978-3-7091-5941-5_4 ◽

1940 ◽

pp. 204-248 ◽

Cited By ~ 9

Author(s):

R. P. Bell

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid

Kinetic evidence for the occurrence of general acid-base catalysis in N-methylhydroxylaminolysis of N-ethoxycarbonylphthalimide (NCPH)

International Journal of Chemical Kinetics ◽

10.1002/(sici)1097-4601(1997)29:9<647::aid-kin1>3.0.co;2-u ◽

1997 ◽

Vol 29 (9) ◽

pp. 647-654 ◽

Cited By ~ 2

Author(s):

M. Niyaz Khan

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid

General Acid–Base Catalysis in Model Systems

Hydrogen-Transfer Reactions ◽

10.1002/9783527611546.ch31 ◽

2007 ◽

pp. 975-1012

Author(s):

Anthony J. Kirby

Keyword(s):

Base Catalysis ◽

Model Systems ◽

Acid Base ◽

General Acid

ChemInform Abstract: Influence of Hydrogen Ion Activity and General Acid-Base Catalysis on the Rate of Decomposition of Hydrogen Peroxide by a Novel Nonaggregating Water-Soluble Iron(III) Tetraphenylporphyrin Derivative.

Chemischer Informationsdienst ◽

10.1002/chin.198648273 ◽

1986 ◽

Vol 17 (48) ◽

Author(s):

M. F. ZIPPLIES ◽

W. A. LEE ◽

T. C. BRUICE

Keyword(s):

Hydrogen Peroxide ◽

Water Soluble ◽

Base Catalysis ◽

Hydrogen Ion ◽

Acid Base ◽

Soluble Iron ◽

General Acid ◽

Ion Activity

Structures of bacterial polynucleotide kinase in a Michaelis complex with GTPMg2+ and 5'-OH oligonucleotide and a product complex with GDPMg2+ and 5'-PO4 oligonucleotide reveal a mechanism of general acid-base catalysis and the determinants of phosphoacceptor recognition

Nucleic Acids Research ◽

10.1093/nar/gkt936 ◽

2013 ◽

Vol 42 (2) ◽

pp. 1152-1161 ◽

Cited By ~ 12

Author(s):

U. Das ◽

L. K. Wang ◽

P. Smith ◽

A. Jacewicz ◽

S. Shuman

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid ◽

Polynucleotide Kinase

Effect of Buffer General Acid−Base Catalysis on the Stereoselectivity of Ester and Thioester H/D Exchange in D2O

Journal of the American Chemical Society ◽

10.1021/ja200014c ◽

2011 ◽

Vol 133 (13) ◽

pp. 5124-5128 ◽

Cited By ~ 9

Author(s):

Jerry R. Mohrig ◽

Nicholas J. Reiter ◽

Randy Kirk ◽

Michelle R. Zawadski ◽

Nathan Lamarre-Vincent

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid

Reverse Protonation Is the Key to General Acid−Base Catalysis in Enolase†,‡

Biochemistry ◽

10.1021/bi0346345 ◽

2003 ◽

Vol 42 (27) ◽

pp. 8298-8306 ◽

Cited By ~ 20

Author(s):

Paul A. Sims ◽

Todd M. Larsen ◽

Russell R. Poyner ◽

W. Wallace Cleland ◽

George H. Reed

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid ◽

Reverse Protonation

Enforced general acid-base catalysis of complex reactions and its limitations

Accounts of Chemical Research ◽

10.1021/ar50108a001 ◽

1976 ◽

Vol 9 (12) ◽

pp. 425-432 ◽

Cited By ~ 128

Author(s):

William P. Jencks

Keyword(s):

Base Catalysis ◽

Acid Base ◽

General Acid

Solution Kinetics of CC-1065 A-Ring Opening: Substituent Effects and General Acid/Base Catalysis

Journal of the American Chemical Society ◽

10.1021/ja057289a ◽

2006 ◽

Vol 128 (11) ◽

pp. 3722-3727 ◽

Cited By ~ 4

Author(s):

Daniel V. LaBarbera ◽

Edward B. Skibo

Keyword(s):

Ring Opening ◽

Substituent Effects ◽

Base Catalysis ◽

Acid Base ◽

General Acid ◽

Kinetics Of ◽

Solution Kinetics

Induced intramolecularity in the reference reaction can be responsible for the low effective molarity of intramolecular general acid-base catalysis

Faculty Opinions recommendation of General acid-base catalysis mediated by nucleobases in the hairpin ribozyme.

General acid base catalysis

Kinetic evidence for the occurrence of general acid-base catalysis in N-methylhydroxylaminolysis of N-ethoxycarbonylphthalimide (NCPH)

General Acid–Base Catalysis in Model Systems

ChemInform Abstract: Influence of Hydrogen Ion Activity and General Acid-Base Catalysis on the Rate of Decomposition of Hydrogen Peroxide by a Novel Nonaggregating Water-Soluble Iron(III) Tetraphenylporphyrin Derivative.

Structures of bacterial polynucleotide kinase in a Michaelis complex with GTP*Mg2+ and 5'-OH oligonucleotide and a product complex with GDP*Mg2+ and 5'-PO4 oligonucleotide reveal a mechanism of general acid-base catalysis and the determinants of phosphoacceptor recognition

Effect of Buffer General Acid−Base Catalysis on the Stereoselectivity of Ester and Thioester H/D Exchange in D2O

Reverse Protonation Is the Key to General Acid−Base Catalysis in Enolase†,‡

Enforced general acid-base catalysis of complex reactions and its limitations

Solution Kinetics of CC-1065 A-Ring Opening: Substituent Effects and General Acid/Base Catalysis

Structures of bacterial polynucleotide kinase in a Michaelis complex with GTPMg2+ and 5'-OH oligonucleotide and a product complex with GDPMg2+ and 5'-PO4 oligonucleotide reveal a mechanism of general acid-base catalysis and the determinants of phosphoacceptor recognition