Imine‐based covalent organic framework as photocatalyst for visible‐light‐induced atom transfer radical polymerization

2021 ◽  
Author(s):  
Xiaoling Fu ◽  
Zhen Lu ◽  
Hongjie Yang ◽  
Xiangyu Yin ◽  
Longqiang Xiao ◽  
...  
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Covalent Organic Framework ◽  
Organic Framework

A covalent organic framework as a photocatalyst for atom transfer radical polymerization under white light irradiation

2021 ◽  
Author(s):  
Zhen Lu ◽  
Xiaoling Fu ◽  
Hongjie Yang ◽  
Yulai Zhao ◽  
Longqiang Xiao ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
White Light ◽  
Light Irradiation ◽  
Atom Transfer ◽  
Co Catalyst ◽  
Covalent Organic Framework ◽  
Organic Framework

TFPPy-Td-COFs have been synthesized to serve as heterogeneous photocatalysts for mediating photo-induced ATRP with copper as a co-catalyst under white light irradiation.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Biomimetic controlled radical photopolymerization in a two-dimensional organized environment under visible light

2021 ◽  
Vol 57 (81) ◽  
pp. 10612-10615
Author(s):  
Sergey A. Dergunov
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Active Role ◽  
Atom Transfer ◽  
Two Dimensional ◽  
Aqueous Conditions

The vesicle bilayer functions as a confined organized environment for the rapid photoinduced atom transfer radical polymerization (photoATRP) of methacrylates under benign aqueous conditions, where accommodation of the monomers plays an active role.

Photoinduced Atom Transfer Radical Polymerization with ppm-Level Cu Catalyst by Visible Light in Aqueous Media

2015 ◽  
Vol 137 (49) ◽  
pp. 15430-15433 ◽  
Author(s):  
Xiangcheng Pan ◽  
Nikhil Malhotra ◽  
Antonina Simakova ◽  
Zongyu Wang ◽  
Dominik Konkolewicz ◽  
...  
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Atom Transfer ◽  
Cu Catalyst ◽  
Ppm Level

Structure-Property Relationships of Core-Substituted Diaryl Dihydrophenazine Organic Photoredox Catalysts and their Application in O-ATRP

2021 ◽  
Author(s):  
Mariel Jene Price ◽  
Katrina Puffer ◽  
Max Kudisch ◽  
Declan Knies ◽  
Garret Miyake
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Low Energy ◽  
Atom Transfer ◽  
Structure Property ◽  
Structure Property Relationships

Photoinduced organocatalyzed atom-transfer radical polymerization (O-ATRP) is a controlled radical polymerization technique that can be driven using low-energy, visible light and makes use of organic photocatalysts. Limitations of O-ATRP have...

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