Conventional radical polymerization and iodine-transfer polymerization of 4′-nonafluorobutyl styrene: Surface and thermal characterizations of the resulting poly(fluorostyrene)s

2013 ◽  
Vol 51 (15) ◽  
pp. 3202-3212 ◽  
Author(s):  
Flavio Ceretta ◽  
Alessandro Zaggia ◽  
Lino Conte ◽  
Bruno Ameduri
Keyword(s):  
Radical Polymerization ◽  
Iodine Transfer

scholarly journals Synthesis of polymethylene-b-poly(vinyl acetate) block copolymer via visible light induced radical polymerization and its application

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42484-42490 ◽  
Author(s):  
HeYing Wang ◽  
Fang Xu ◽  
Kun Cui ◽  
Hao Zhang ◽  
Jin Huang ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Visible Light ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Iodine Transfer

Polymethylene-b-poly(vinyl acetate) block copolymers were synthesized by polyhomologation of ylides and visible light-induced degenerative iodine transfer polymerization of vinyl acetate.

Use of Fluorinated Organic Compounds in Living Radical Polymerizations

2002 ◽  
Vol 67 (10) ◽  
pp. 1383-1415 ◽  
Author(s):  
Patrick Lacroix-Desmazes ◽  
Bruno Améduri ◽  
Bernard Boutevin
Keyword(s):  
Radical Polymerization ◽  
Organic Compounds ◽  
Alkyl Halides ◽  
Huge Number ◽  
Star Copolymers ◽  
Reversible Addition ◽  
Living Radical Polymerizations ◽  
Iodine Transfer ◽  
Controlled Living Radical Polymerization ◽  
Number Of Publications

Controlled/living radical polymerization (LRP) is a field of special interest because it allows tailoring well-defined macromolecular architectures such as telechelic, block, graft or star copolymers. Since the eighties, several techniques have been reported [such as the iniferter method, nitroxide-mediated radical polymerization (NMP), atom transfer radical polymerization (ATRP), iodine transfer polymerization (ITP), and reversible addition-fragmentation chain transfer (RAFT)] giving rise to a huge number of publications and patents. This review aims at illustrating the contribution of fluorinated organic compounds in this area of research through the use of fluorinated initiators (dithiocarbamates, xanthates, tetraphenylethanes, alkoxyamines, fluorinated alkyl halides, and dithioesters) or other fluorinated molecules (ligands, solvents). Another point depicts the LRP of various fluorinated monomers (methacrylates, acrylates, styrenics, and alkenes). Finally, fluorinated block and graft copolymers prepared by LRP have been reported. A review with 165 references.

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