scholarly journals Synthesis of polymethylene-b-poly(vinyl acetate) block copolymer via visible light induced radical polymerization and its application

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42484-42490 ◽  
Author(s):  
HeYing Wang ◽  
Fang Xu ◽  
Kun Cui ◽  
Hao Zhang ◽  
Jin Huang ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Visible Light ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Iodine Transfer

Polymethylene-b-poly(vinyl acetate) block copolymers were synthesized by polyhomologation of ylides and visible light-induced degenerative iodine transfer polymerization of vinyl acetate.

Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

2020 ◽  
Vol 11 (18) ◽  
pp. 3251-3259
Author(s):  
Haoyu Yu ◽  
Jianwei Shao ◽  
Dong Chen ◽  
Li Wang ◽  
Wantai Yang
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Control Radical Polymerization ◽  
Strong Ability

TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.

Photoinduced controlled radical polymerization of methyl acrylate and vinyl acetate by xanthate

2018 ◽  
Vol 9 (21) ◽  
pp. 2897-2904 ◽  
Author(s):  
Jiajia Li ◽  
Xiangqiang Pan ◽  
Na Li ◽  
Jian Zhu ◽  
Xiulin Zhu
Keyword(s):  
Block Copolymer ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization

A block copolymer of PMA-b-PVAc was successfully synthesized using photo-induced RAFT polymerization with a xanthate.

Synthesis of poly(vinyl acetate)-b-poly(vinyl chloride) block copolymers by Cobalt-Mediated Radical Polymerization (CMRP)

2013 ◽  
Vol 4 (5) ◽  
pp. 1685 ◽  
Author(s):  
Yasmine Piette ◽  
Antoine Debuigne ◽  
Vincent Bodart ◽  
Nicolas Willet ◽  
Anne-Sophie Duwez ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Vinyl Chloride ◽  
Poly Vinyl Chloride

Synthesis and Self-Assemble Behavior of Block Copolymerization of Vinyl Acetate and N-Vinylacetamide

2013 ◽  
Vol 645 ◽  
pp. 10-14
Author(s):  
Yu Lou ◽  
Dong Jian Shi ◽  
Wei Fu Dong ◽  
Ming Qing Chen
Keyword(s):  
Block Copolymer ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Microphase Separation ◽  
Molar Ratio ◽  
Block Copolymerization ◽  
Bulk State ◽  
Self Assembled

Polymerizations of VAc was carried out using AIBN as the initiator and DIP as the MADIX agent precursor. Then, block copolymer PVAc-b-PNVA had been synthesized by RAFT radical polymerization in the presence of PVAc-DIP as macro CTA. The length of blocks could be tuned by changing the molar ratio of NVA and VAc. Block copolymer PVAc-b-PNVA self-assembled into micelles in solution, and underwent microphase separation in bulk state.

Atom transfer radical polymerization of (meth)acrylates and their novel block copolymers with vinyl acetate

2003 ◽  
Vol 39 (11) ◽  
pp. 2193-2201 ◽  
Author(s):  
Mohammad Ali Semsarzadeh ◽  
Ahmad Mirzaei ◽  
Ebrahim Vasheghani-Farahani ◽  
Mehdi Nekoomanesh Haghighi
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Atom Transfer

Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

2017 ◽  
Vol 8 (19) ◽  
pp. 2899-2903 ◽  
Author(s):  
Cansu Aydogan ◽  
Ceren Kutahya ◽  
Andrit Allushi ◽  
Gorkem Yilmaz ◽  
Yusuf Yagci
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Metal Free

A completely metal-free strategy was developed by combining Atom Transfer Radical Polymerization (ATRP) and Ring Opening Polymerization (ROP) for the syntheses of block copolymers.

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