Highly efficient near-infrared to visible upconversion luminescence in transparent glass ceramics containing Yb3+/Er3+:NaYF4nanocrystals

2008 ◽  
Vol 205 (7) ◽  
pp. 1680-1684 ◽  
Author(s):  
Ping Huang ◽  
Feng Liu ◽  
Daqin Chen ◽  
Yuansheng Wang ◽  
Yunlong Yu
Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1033
Author(s):  
Jianfeng Li ◽  
Yi Long ◽  
Qichao Zhao ◽  
Shupei Zheng ◽  
Zaijin Fang ◽  
...  

Transparent glass-ceramic composites embedded with Ln-fluoride nanocrystals are prepared in this work to enhance the upconversion luminescence of Tm3+. The crystalline phases, microstructures, and photoluminescence properties of samples are carefully investigated. KYb3F10 nanocrystals are proved to controllably precipitate in the glass-ceramics via the inducing of Yb3+ when the doping concentration varies from 0.5 to 1.5 mol%. Pure near-infrared upconversion emissions are observed and the emission intensities are enhanced in the glass-ceramics as compared to in the precursor glass due to the incorporation of Tm3+ into the KYb3F10 crystal structures via substitutions for Yb3+. Furthermore, KYb2F7 crystals are also nano-crystallized in the glass-ceramics when the Yb3+ concentration exceeds 2.0 mol%. The upconversion emission intensity of Tm3+ is further enhanced by seven times as Tm3+ enters the lattice sites of pure KYb2F7 nanocrystals. The designed glass ceramics provide efficient gain materials for optical applications in the biological transmission window. Moreover, the controllable nano-crystallization strategy induced by Yb3+ opens a new way for engineering a wide range of functional nanomaterials with effective incorporation of Ln3+ ions into fluoride crystal structures.


2010 ◽  
Vol 486 (4-6) ◽  
pp. 126-129 ◽  
Author(s):  
Degang Deng ◽  
Shiqing Xu ◽  
Haidong Ju ◽  
Shilong Zhao ◽  
Huanping Wang ◽  
...  

2015 ◽  
Vol 409 ◽  
pp. 54-62 ◽  
Author(s):  
O.S. Dymshits ◽  
P.A. Loiko ◽  
N.A. Skoptsov ◽  
A.M. Malyarevich ◽  
K.V. Yumashev ◽  
...  

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