Effect of Solid Dilution and Temperature on the Crystal Field Spectra of Chromium Ions in Single Crystals of Chrome Alum

We have extended the low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 600 p.p.m. manganese from magnetic fields of 9 to 56 kG. The crystal field splitting parameters determined at low magnetic fields also characterizes the magnetic anisotropy at high magnetic fields. Manganese–manganese interaction effects are observed in the magnetic anisotropy at manganese concentrations greater than 300 p.p.m. Low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 164 p.p.m. chromium are reported and indicate a crystal field splitting of 0.16 K for the chromium ion.

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Spectroscopic studies and crystal-field analysis of U3+ ions in RbY2Cl7 single crystals

The Journal of Chemical Physics ◽

10.1063/1.473050 ◽

1997 ◽

Vol 106 (8) ◽

pp. 3067-3077 ◽

Cited By ~ 24

Author(s):

M. Karbowiak ◽

J. Drozdzynski ◽

K. M. Murdoch ◽

N. M. Edelstein ◽

S. Hubert

Keyword(s):

Single Crystals ◽

Crystal Field ◽

Spectroscopic Studies ◽

Field Analysis

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Crystal field of Dy implanted in Au single crystals, obtained by Mossbauer spectroscopy

Journal of Physics F Metal Physics ◽

10.1088/0305-4608/11/3/005 ◽

1981 ◽

Vol 11 (3) ◽

pp. 547-556 ◽

Cited By ~ 9

Author(s):

P J Kikkert ◽

L Niesen

Keyword(s):

Mössbauer Spectroscopy ◽

Single Crystals ◽

Crystal Field ◽

Mossbauer Spectroscopy ◽

Mößbauer Spectroscopy

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Free ion and crystal field splitting of Tm3+ in single crystals of thulium sulfate octahydrate

Chemical Physics ◽

10.1016/0301-0104(75)85014-2 ◽

1975 ◽

Vol 10 (1) ◽

pp. 131-139 ◽

Cited By ~ 6

Author(s):

Edwin A. Karlow ◽

Joachim Stöhr ◽

John B. Gruber

Keyword(s):

Single Crystals ◽

Crystal Field ◽

Crystal Field Splitting ◽

Field Splitting ◽

Free Ion

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New Developments in Raman Spectroscopy with Lasers: Electronic Transitions

Applied Spectroscopy ◽

10.1366/000370268774384597 ◽

1968 ◽

Vol 22 (5) ◽

pp. 438-444 ◽

Cited By ~ 17

Author(s):

J. A. Koningstein

Keyword(s):

Raman Spectroscopy ◽

Single Crystals ◽

Crystal Field ◽

Raman Spectra ◽

Raman Effect ◽

Electronic Transitions ◽

New Developments ◽

Selection Rules ◽

Phonon Spectra ◽

Host Lattices

A discussion is given of the Raman spectra of single crystals of yttrium gallium garnet (YGaG), of ytterbrium gallium garnet (YbGaG), and of Yb:YGaG. From a comparison of the spectra it has been possible to separate the phonon spectra of the host lattices from that of an electronic Raman effect which occurs between the crystal field levels of the 2F7/2 manifold of Yb3+ in the garnet crystals. Information with respect to the selection rules governing both types of spectra is given.

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