Can metal halides be electron donors in σ‐hole and π‐hole tetrel bonds? Cooperativity with an alkaline‐earth bond

2021 ◽  
Author(s):  
Na Liu ◽  
Qingzhong Li
Keyword(s):  
Alkaline Earth ◽  
Electron Donors ◽  
Metal Halides ◽  
Tetrel Bonds

scholarly journals Kinetic study of wood pyrolysis in presence of metal halides

2014 ◽  
Vol 12 (12) ◽  
pp. 1294-1303 ◽  
Author(s):  
Vladimir Beliy ◽  
Elena Udoratina
Keyword(s):  
Activation Energy ◽  
Lewis Acids ◽  
Alkaline Earth ◽  
Reaction Order ◽  
Earth Metal ◽  
Inorganic Salts ◽  
Alkaline Earth Metal ◽  
Metal Halides ◽  
Wood Pyrolysis ◽  
Kinetics Of

AbstractThe purpose of this work was to study the kinetics of wood pyrolysis in the presence of inorganic salts, representatives of classes of alkali and alkaline earth metal halides (NaCl, KCl, KBr, CaCl2, BaCl2·2H2O) and Lewis acids (AlCl3·6H2O, FeCl3·6H2O, CuCl2, CuBr2, ZnCl2·1.5H2O, NiCl2·6H2O, SnCl2·2H2O) using TG-DSC. The activity of these catalysts was estimated by the temperature of the beginning of pyrolysis, charcoal yield and kinetic parameters, such as energy of activation and reaction order. Using the Lewis acids as catalysts for pyrolysis leads to a decrease in the temperature of the process beginning and the activation energy. In the presence of other catalysts activation energy does not significantly change. The increase of a seeming reaction order in the presence of Lewis acids possibly is a consequence of complication of the thermodestruction mechanism, with the appearance of new parallel competing stages.

Surface Tension of Fused Alkaline Earth Metal Halides

1958 ◽  
Vol 62 (6) ◽  
pp. 766-766 ◽  
Author(s):  
Richard B. Ellis ◽  
Josiah E. Smith ◽  
Evelyn B. Baker
Keyword(s):  
Surface Tension ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Halides

Dehydration energies of alkaline earth metal halides – a novel simulation methodology

2005 ◽  
Vol 310 (1-3) ◽  
pp. 59-66 ◽  
Author(s):  
V. Sudha ◽  
S. Harinipriya ◽  
M.V. Sangaranarayanan
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Halides ◽  
Simulation Methodology
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