The entropy of liquid mixtures: I. The theory of Raoult's Law

1941 ◽  
Vol 60 (2) ◽  
pp. 76-84 ◽  
Author(s):  
A. J. Staverman ◽  
J. H. van Santen
Keyword(s):  
Liquid Mixtures ◽  
Raoult’S Law ◽  
Raoult's Law

Deviations from Raoult's Law in H2O + D2O Liquid Mixtures

1979 ◽  
Vol 32 (1) ◽  
pp. 197 ◽  
Author(s):  
RC Phutela ◽  
DV Fenby
Keyword(s):  
Vapour Pressure ◽  
Boiling Point ◽  
Liquid Mixture ◽  
Isotope Effects ◽  
Liquid Mixtures ◽  
Raoult’S Law ◽  
Ideal Solutions ◽  
Good Agreement ◽  
Raoult's Law

Deviations from Raoult's law in H2O+D2O liquid mixtures are calculated from vapour pressure isotope effects for HDO and D2O by assuming that the equilibrium H2O+ HDO+D2O liquid mixtures are ideal solutions. The results are in good agreement with those obtained experimentally from liquid-mixture vapour pressure and boiling point measurements.

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