Catalysis of Forward and Reverse Reactions of ϵ-Caprolactam-Blocked Polyisocyanate: Double Arrhenius Plots and Equilibrium Temperatures of a Thermally Reversible Reaction

2017 ◽  
Vol 2 (29) ◽  
pp. 9586-9594 ◽  
Author(s):  
George Libni ◽  
Abdulsalam Sultan Nasar
Keyword(s):  
Reversible Reaction ◽  
Arrhenius Plots

scholarly journals Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

2015 ◽  
Vol 44 (11) ◽  
pp. 5041-5044 ◽  
Author(s):  
Susana Luaces ◽  
Ramón Macías ◽  
María José Artigas ◽  
Fernando J. Lahoz ◽  
Luis A. Oro
Keyword(s):  
Reversible Reaction ◽  
Synthesis And Characterization ◽  
Reaction Cycles

New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by the hydrogenation of the alkene ligand.

Mapping the kinetic events in a linear two-step irreversible-reversible reaction mechanism

2017 ◽  
Vol 158 ◽  
pp. 370-380 ◽  
Author(s):  
Daniel Branco P. ◽  
Gregory S. Yablonsky ◽  
Guy B. Marin ◽  
Denis Constales
Keyword(s):  
Reaction Mechanism ◽  
Reversible Reaction

Temperature “breaks” in Arrhenius plots: A thermodynamic consequence of a phase change

1971 ◽  
Vol 31 (1) ◽  
pp. 47-51 ◽  
Author(s):  
Junh Kumamoto ◽  
John K. Raison ◽  
James M. Lyons
Keyword(s):  
Phase Change ◽  
Arrhenius Plots

Dynamic combinatorial chemistry with diselenides and disulfides in water

2014 ◽  
Vol 50 (28) ◽  
pp. 3716-3718 ◽  
Author(s):  
Brian Rasmussen ◽  
Anne Sørensen ◽  
Henrik Gotfredsen ◽  
Michael Pittelkow
Keyword(s):  
Combinatorial Chemistry ◽  
Reversible Reaction ◽  
Dynamic Combinatorial Chemistry

Diselenide exchange is introduced as a reversible reaction in dynamic combinatorial chemistry in water at physiological pH.

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